[Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]

Base Information

Chemical Name:[Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]
CAS No.:199733-44-3
Molecular Formula:C₃₂H₂₆B₂F₄FeN₆O₄
Molecular Weight:712.059
Hs Code.:

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Chemical Property of [Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]

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Technology Process of [Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]

There total 1 articles about [Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: iron(II)bis(α-benzoyldioximate)(py)2

: 109-63-7
trifluoroborane diethyl ether

: 75-05-8,26809-02-9
acetonitrile

: 199733-44-3
[Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]

Guidance literature:: In diethyl ether; acetonitrile; Fe-contg. compd. (156 mmol) was suspended in Et2O-MeCN mixt. with stirring; BF3*Et2O (690 mmol) was added dropwise under Ar; stirring for 30 min; the react. mixt. was filtered; the solid was washed with Et2O, acetone-CH3CN mixt., Et2O-CH3CN mixt., hexane-hexamethyldisiloxane mixt., and then with hexane, and dried in vac.;
DOI:10.1039/b107021p

Reference yield: 63.0%

: 199733-44-3
[Fe(α-benzyldioximato)2(BF2)2(acetonitrile)2]

: 2038-44-0
dichloroglyoxime

: 380456-14-4
FeBd2(Cl2Gm)(BF)2

Guidance literature:: With triethylamine; BF₃*OEt₂; In nitromethane; Fe-contg. compd. and an excess of dichloroglyoxime were dissolved/suspended in dry nitromethane-hexamethyldisiloxane mixt. with stirring under Ar; NEt3, BF3OEt2 and chloroform were added dropwise; heating to b.p.; BF3*OEt2 addn.; the solvent was distd. off with stirring; the mixt. was allowed to cool to room temp.; the solid was filtered off, washed with methanol, Et2O, and then with hexane, and dried in vac.; elem. anal.;
DOI:10.1039/b107021p