MeN(CH₂-2-C₆H₄BiPh₂)2

Base Information

Chemical Name:MeN(CH₂-2-C₆H₄BiPh₂)2
CAS No.:1266397-36-7
Molecular Formula:C₃₉H₃₅Bi₂N
Molecular Weight:935.674
Hs Code.:

MeN(CH<sub>2</sub>-2-C<sub>6</sub>H<sub>4</sub>BiPh<sub>2</sub>)2

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Chemical Property of MeN(CH₂-2-C₆H₄BiPh₂)2

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Technology Process of MeN(CH₂-2-C₆H₄BiPh₂)2

There total 1 articles about MeN(CH₂-2-C₆H₄BiPh₂)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 27.0%

: 39248-62-9
diphenylbismuthanyl bromide

: 7375-70-4
N⁽¹⁾,N⁽²⁾-bis(2-bromobenzyl)-N⁽¹⁾,N⁽²⁾-dimethylpropane-1,3-diamine

: MeN(CH₂-2-C₆H₄)2BiBr

: 1266397-36-7
MeN(CH₂-2-C₆H₄BiPh₂)2

Guidance literature:: With n-BuLi; In diethyl ether; hexane; (N2); std. Schlenk technique; soln. of BuLi in hexane was added dropwiseto soln. of MeN(CH2C6H4Br)2 in Et2O at -78°C; stirred for 2 h; s lowly warmed to room temp.; Bi compd. was added; stirred at room temp. for 16 h; distd. H2O added; org. layer septd.; aq. phase washed (Et2O); org. phasedried (MgSO4); filtered; evapd. (vac.); elem. anal.;
DOI:10.1021/om1010148

Reference yield: 48.0%

: 109-99-9,24979-97-3,77392-70-2
tetrahydrofuran

: 1266397-36-7
MeN(CH₂-2-C₆H₄BiPh₂)2

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: 1313516-09-4
[(Cr(CO)5)2(MeN(CH₂-2-C₆H₄BiPh₂)2]

Guidance literature:: In tetrahydrofuran; Irradiation (UV/VIS); (N2); photolysis of THF soln. of chromium compd. for 1 h, addn. of THF soln. of bismuth compd., stirring for 1 h; evapn., addn. of hexane, filtration, evapn., IR and NMR;
DOI:10.1039/c1dt10447k

Reference yield: 26.0%

: 14104-20-2
silver tetrafluoroborate

: 12078-28-3,38979-86-1
dicarbonylcyclopentadienyliodoiron(II)

: 1266397-36-7
MeN(CH₂-2-C₆H₄BiPh₂)2

: [((C₅H₅)Fe(CO)2)2(MeN(CH₂-2-C₆H₄BiPh₂)2)][BF₄]2

Guidance literature:: In tetrahydrofuran; dichloromethane; (N2); std. Schlenk technique; Fe complex was dissolved in CH2Cl2/THF (1 drop); added to soln. of Ag salt in CH2Cl2; stirred for 2 h in dark; filtered; soln. of Bi compd. in CH2Cl2 was added; stirred for 16 h at room temp.; concd. (vac.); hexane added; filtered; dried (vac.);
DOI:10.1021/om1010148