tributyl(1-phenylprop-1-en-1-yl)stannane

Base Information

• Chemical Name: tributyl(1-phenylprop-1-en-1-yl)stannane
• CAS No.: 125405-88-1
• Molecular Formula: C₂₁H₃₆Sn
• Molecular Weight: 407.227
• Mol file: 125405-88-1.mol

Synonyms:

Chemical Property of tributyl(1-phenylprop-1-en-1-yl)stannane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tributyl(1-phenylprop-1-en-1-yl)stannane

There total 3 articles about tributyl(1-phenylprop-1-en-1-yl)stannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

1-Phenylprop-1-yne (673-32-5) + tri-n-butyl-tin hydride (688-73-3) → (E)-tributyl(1-phenylprop-1-en-2-yl)stannane (124582-43-0,131428-21-2) + E-tributyl-1-phenyl-propenylstannane (112713-91-4,125405-88-1)

Guidance literature:

tetrakis(triphenylphosphine) palladium⁽⁰⁾; In benzene; hydrostannylation, at room temperature, mixture was stood for 10 minutes; removal of solvent (vacuo), flash chromy. (silica gel, dichloromethane);

Reference yield:

1-Phenylprop-1-yne (673-32-5) + tri-n-butyl-tin hydride (688-73-3) → tributyl(1-phenylprop-1-en-1-yl)stannane (125405-88-1,112713-91-4) + (Z)-tributyl(1-phenylprop-1-en-2-yl)stannane (124582-43-0,131428-21-2)

Guidance literature:

With C₃₃H₄₆PRuS⁽¹⁺⁾*C₃₂H₁₂BF₂₄^(1-); In chlorobenzene; at 80 ℃; for 24h; Glovebox; Inert atmosphere; Sealed tube;

DOI:10.1021/jacs.7b13088

Reference yield:

1-Phenylprop-1-yne (673-32-5) + tri-n-butyl-tin hydride (688-73-3) → (E)-tributyl(1-phenylprop-1-en-2-yl)stannane (124582-43-0,131428-21-2) + 1-(tributylstannyl)-1-phenyl-1-propene (125405-88-1,112713-91-4)

Guidance literature:

With [MoI₂(CO)2(CNC₆H₃(C₆H₃iPr₂-2,6)2-2,6)2]; In benzene-d6; at 20 ℃; for 0.5h; Overall yield = 94 %; Overall yield = 114 mg; Inert atmosphere; Schlenk technique; Glovebox;

DOI:10.1002/anie.201802397

upstream raw materials:

1-Phenylprop-1-yne

tri-n-butyl-tin hydride

Downstream raw materials:

4-phenylquinoline

2-methyl-3-phenyl-1H-indole

1-nitro-2-(1-phenyl-1-propen-1-yl)benzene

1H-2,3-benzoxazin-1-one