fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3

Base Information

• Chemical Name: fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3
• CAS No.: 97202-30-7
• Molecular Formula: C₃₂H₃₃MoO₆P₃
• Molecular Weight: 702.472
• Mol file: 97202-30-7.mol

Synonyms:

Chemical Property of fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3

There total 2 articles about fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

(1,2-bis(diphenylphosphino)ethane)tetracarbonylmolybdenum (15444-66-3) + phosphorous acid trimethyl ester (121-45-9) → fac-{(P(OMe)3)-1,2-bis(diphenylphosphino)ethane}Mo(CO)3 (97202-30-7)

Guidance literature:

In tetrahydrofuran; byproducts: CO; Irradiation (UV/VIS); Mo-complex was reacted with P(OMe)3 under photochemical condition;; not isolated; monitored by NMR;;

DOI:10.1016/S0020-1693(00)86034-X

Reference yield:

fac-tricarbonyl-bis(diphenylphosphino)ethane-η2-sulfur dioxide-molybdenum (82630-14-6,84580-19-8,82630-11-3) + phosphorous acid trimethyl ester (121-45-9) → fac-Mo(CO)3(Ph2PC2H4PPh2)(P(OCH3)3) (97202-30-7)

Guidance literature:

In dichloromethane; byproducts: SO2; mixing Mo-compd. soln. with various amounts of ligand soln. (Schlenk tube, -78°C), solvent addn., mixt. transfer into IR cell (syringe),equilibration to const. temp.; Kinetics;

DOI:10.1016/0020-1693(95)04649-6

upstream raw materials:

(1,2-bis(diphenylphosphino)ethane)tetracarbonylmolybdenum

phosphorous acid trimethyl ester

fac-tricarbonyl-bis(diphenylphosphino)ethane-η2-sulfur dioxide-molybdenum

Refernces