Ru(CH₃OC₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)

Base Information

• Chemical Name: Ru(CH₃OC₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)
• CAS No.: 444017-92-9
• Molecular Formula: C₅₂H₄₄ClNO₃P₂Ru
• Molecular Weight: 929.397
• Mol file: 444017-92-9.mol

Synonyms:

Chemical Property of Ru(CH₃OC₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Ru(CH₃OC₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO)

There total 1 articles about Ru(CH₃OC₆H₄NHCHC₆H₂CH₃O)(P(C₆H₅)3)2Cl(CO) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

tris(triphenylphosphine)ruthenium(II) chloride (15529-49-4,41756-81-4) + 2-formyl-4-methyl-6-((p-methoxyphenylimino)methyl)phenol (222532-55-0) → Ru(η2-C6H2O-2-CHNHC6H4OMe(p)-3-Me-5)(PPh3)2(CO)Cl (444017-92-9,188547-18-4)

Guidance literature:

In ethanol; byproducts: HCl, PPh3; reflux; elem. anal.;

DOI:10.1016/S0277-5387(96)00390-7

Reference yield: 98.0%

[Ru(CH3OC6H4NHCHC6H2(CH3)(O))(P(C6H5)3)2(CO)Cl] (444017-92-9,188547-18-4) + propargyl alcohol (107-19-7) → [Ru(CH3OC6H4NHCHC6H2(CH3)(O)C(CH2OH)CH)(P(C6H5)3)2(CO)Cl] (336142-28-0)

Guidance literature:

In methanol; dichloromethane; excess of HOCH2C2H used; stirred at 40°C; concd., crystd. on cooling, collected, washed (MeOH), dried (vac.); elem. anal.;

DOI:10.1021/om000649c

Reference yield: 92.0%

Ru(CH3OC6H4NHCHC6H2CH3O)(P(C6H5)3)2Cl(CO) (188547-18-4,444017-92-9) + carbon monoxide (201230-82-2) → Ru(CH3OC6H4NHCHC6H2CH3OCO)(P(C6H5)3)2Cl(CO)

Guidance literature:

In dichloromethane; N2 was passed through a soln. of complex in CH2Cl2 for 15 min followed by CO (1 atm) for 10 min, the soln. was left under CO atm for 12 h with constant stirring; evapd. under reduced pressure, dissolved in min CH2Cl2, petroleum ether was added, crystals were dried in vac.; elem. anal.;

DOI:10.1016/j.jorganchem.2005.04.012

upstream raw materials:

tris(triphenylphosphine)ruthenium(II) chloride

2-formyl-4-methyl-6-((p-methoxyphenylimino)methyl)phenol

Downstream raw materials:

[Ru(CH₃OC₆H₄NHCHC₆H₂(CH₃)(O)C(CH₂OH)CH)(P(C₆H₅)3)2(CO)Cl]

[Ru(CH₃OC₆H₄NHCHC₆H₂(CH₃)(O)C(C₆H₅)CH)(P(C₆H₅)3)2(CO)Cl]

[Ru(η1-C6H2OH-2-CHNC6H4OMe(p)-3-Me-5)(PPh3)2(CO)(2,2'-bipyridine)](PF6)

[Ru(η1-C6H2OH-2-CHNC6H4OMe(p)-3-Me-5)(PPh3)2(CO)(1,10-phenanthroline)](PF6)