Technology Process of (C5H4CH2CH2OCH3)Ti(O-2,6-(t)Bu2-4-MeC6H2)Cl2
There total 1 articles about (C5H4CH2CH2OCH3)Ti(O-2,6-(t)Bu2-4-MeC6H2)Cl2 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
diethyl ether;
under Ar atm. to suspn. Ti complex in Et2O at -30°C soln. Li(O-2,6-(t)Bu2-4-MeC6H2) in Et2O was added, warmed slowly to room temp. ans stirred overnight; soln. was filtered, concd., and kept at -78°C for 15 h, ppt. was dried in vacuo; elem. anal.;
DOI:10.1021/om051031b
- Guidance literature:
-
In
tetrahydrofuran; diethyl ether;
under Ar atm. to suspn. Ti complex in Et2O at -40°C 1 equiv. soln. MeMgCl in THF was added dropwise, warmed slowly to room temp. and stirred for 10 h; volatiles were removed in vacuo, residue was extd. with pentane, soln. was evapd. in vacuo; elem. anal.;
DOI:10.1021/om051031b
- Guidance literature:
-
In
tetrahydrofuran; diethyl ether;
under Ar atm. to suspn. Ti complex in Et2O at -40°C 2 equiv. soln. MeMgCl in THF was added dropwise, warmed slowly to room temp. and stirred for 10 h; volatiles were removed in vacuo, residue was extd. with pentane, soln. was evapd. in vacuo; elem. anal.;
DOI:10.1021/om051031b
