((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾

Base Information

Chemical Name:((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾
CAS No.:113095-53-7
Molecular Formula:C₄₄H₄₄NiO₆P₂
Molecular Weight:789.467
Hs Code.:

((Me-2-C<sub>6</sub>H<sub>4</sub>O)3P)2mono(ethyne)nickel<sup>(0)</sup>

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾

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Technology Process of ((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾

There total 2 articles about ((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 42.0%

: 50696-82-7
tris(ethene)nickel⁽⁰⁾

: 2622-08-4
tri(O-methylphenyl)phosphite

: 74-86-2,25067-58-7
acetylene

: 113095-53-7
((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾

Guidance literature:: In diethyl ether; P(OC6H4CH3)3 in ether added to Ni-complex in ether at -30°C under Ar, filtered to remove insol. impurities, ethyne added at -78°C,light yellow pptn.; mother liquor sepd. (capillary), washed (cold pentane), dried (vac., -30°C), elem. anal.;
DOI:10.1021/ja00197a029

Reference yield:

: 31666-47-4
π-C2H4Ni(P(OC6H4CH3-o)3)2

: 74-86-2,25067-58-7
acetylene

: 113095-53-7
((Me-2-C₆H₄O)3P)2mono(ethyne)nickel⁽⁰⁾

Guidance literature:: In tetrahydrofuran; THF soln. of stoich. amount of acetylene was added at 20°C under Ar to a THF soln. of Ni-complex; solvent was removed under vac., residue was treated with cold pentane, filtered off and dried; elem. anal.;
DOI:10.1016/0022-328X(87)80329-7