[Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)]

Base Information

• Chemical Name: [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)]
• CAS No.: 778610-75-6
• Molecular Formula: C₂₄H₂₇Mo₂PS₂
• Molecular Weight: 602.464
• Mol file: 778610-75-6.mol

Synonyms:

Chemical Property of [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)]

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)]

There total 1 articles about [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 75.0%

sodium tetrahydroborate (16940-66-2) + [(η5-cyclopentadienyl)2Mo2(μ-CHN(t-Bu)(μ-SMe)2(μ-PPh2)] (192637-71-1,779340-58-8) → [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)] (778610-75-6)

Guidance literature:

In tetrahydrofuran; byproducts: NaCl; under inert atm. soln. (Mo2Cp2(μ-SMe)2(μ-Cl)(μ-PPh2)) in THF was stirred with NaBH4 for 1 h at room temp.; solvent was removed in vacuo, residue was extd. with Et2O, volatiles were evapd.; elem. anal.;

DOI:10.1039/b407564a

Reference yield: 85.0%

dichloromethane (75-09-2) + [Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)] (778610-75-6) + tert-butylisonitrile (119072-55-8,7188-38-7) → (Mo2(C5H5)2(SCH3)2(HCNC(CH3)3)(P(C6H5)2))*0.25CH2Cl2

Guidance literature:

In tetrahydrofuran; under inert atm. to soln. (Mo2Cp2(μ-SMe)2(μ-H)(μ-PPh2)) in THF t-BuNC was added at room temp.; solvent was removed in vacuo, residue was extd. with Et2O, volatiles were removed, residue was dissolved in CH2Cl2, chromy. on florisil (CH2Cl2), solvent was evapd.; elem. anal.;

DOI:10.1039/b407564a

upstream raw materials:

sodium tetrahydroborate

[(η5-cyclopentadienyl)2Mo2(μ-CHN(t-Bu)(μ-SMe)2(μ-PPh2)]