(N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II)

Base Information

• Chemical Name: (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II)
• CAS No.: 400608-68-6
• Molecular Formula: C₂₂H₃₀N₂Pt
• Molecular Weight: 517.574

Synonyms:

Chemical Property of (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II)

Chemical Property:

Purity/Quality:

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Technology Process of (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II)

There total 1 articles about (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1,4-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene + [PtMe2(SMe2)]2 → (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II) (400608-68-6)

Guidance literature:

In toluene; under Ar atm. (Me2Pt(SMe2))2 was dissolved in toluene, α-diimine was added and stirred overnight at r.t.; solvent was reduced, p.e. was added, product was filtered; elem. anal.;

DOI:10.1002/1522-2675(20011017)84:10<3247::AID-HLCA3247>3.0.CO;2-W

Reference yield: 54.0%

(N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II) (400608-68-6) + water (7732-18-5) + dihydrogen peroxide (7722-84-1) → (3,5-(CH3)2C6H3-N=C(CH3)-C(CH3)=N-3,5-(CH3)2C6H3)Pt(IV)(CH3)3(OH)2 (674779-42-1)

Guidance literature:

With Na₂S₂O₃; In water; acetone; to suspn. Pt(II) complex in acetone at -30°C H2O2/H2O was added over several hours while raising temp. slowly to -10°C; excess H2O2 was quenched with aq. Na2S2O3, volatiles were evapd., residue was washed with pentane and dried under vac.;

DOI:10.1039/b304475k

Reference yield: 43.0%

tetrafluoroboric acid + (N,N'-bis(3,5-dimethylphenyl)-2,3-dimethyl-1,4-diaza-1,3-butadiene)dimethylplatinum(II) (400608-68-6) + carbon monoxide (201230-82-2) → Pt(CH3)CO((CH3)2C6H3NCCH3)2(1+)*BF4(1-)=PtCH3CO((CH3)2C6H3NCCH3)2BF4 (404373-74-6)

Guidance literature:

In water; to suspn. of Pt-complex in trifluoroethanol was added aq. soln. of HBF4,stirred at room temp. for few min, flask was degassed and filled with 1 atm of CO, stirred under 1 atm of CO for 24 h; solvent was removed at -20°C to 0°C in vacuo, petroleum ether was added, dried for 30 min;

DOI:10.1021/ja011189x

Downstream raw materials:

(3,5-Me₂PhDAB(Me))PtI₂Me₂

[PtPh(N(3,5-Me₂C₆H₃)CMe)2(trifluoroethanol-d3)](CF₃CD₂OB(C₆F₅)3)

Pt(CH₃)CO((CH₃)2C₆H₃NCCH₃)2⁽¹⁺⁾*BF₄^(1-)=PtCH₃CO((CH₃)2C₆H₃NCCH₃)2BF₄

(C₆H₃(CH₃)2NC(CH₃))2Pt(CH₂C₆H₄CH₃)(NCCH₃)⁽¹⁺⁾*BF₄^(1-)=(C₁₀H₁₂N)2PtC₈H₉(NCCH₃)BF₄

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