Technology Process of trans-RuHI[PPh(OEt)2]4
There total 4 articles about trans-RuHI[PPh(OEt)2]4 which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
In
ethanol;
byproducts: H2; Ru compd. and an excess of LiI were treated with ethanol after cooling to -80°C; the mixt. was stirred under an inert atmosphere for 1 h; the vol. of the soln. was reduced by evapn. under reduced pressure; cooling to -25°C; the solid was filtered off and dried under vac.; elem. anal.;
DOI:10.1039/b004833j
- Guidance literature:
-
In
ethanol;
byproducts: H2; Ru compd. and an excess of NaI were treated with ethanol after cooling to -80°C; the mixt. was stirred under an inert atmosphere for 1 h; the vol. of the soln. was reduced by evapn. under reduced pressure; cooling to -25°C; the solid was filtered off and dried under vac.; elem. anal.;
DOI:10.1039/b004833j
- Guidance literature:
-
With
CF3SO3Me;
In
ethanol; toluene;
byproducts: CH4; to a soln. of Ru compd. in toluene cooled to -80°C CF3SO3Me was added; mixt. was stirred at 0°C under an inert atmosphere for 30 min; excess of NaI in EtOH was added; stirring for 1 h; solvent was removed under reduced pressure; oily residue was treated with ethanol; cooling to -25°C; the solid was filtered off and driedunder vac.; elem. anal.;
DOI:10.1039/b004833j
![[RuH(η2-H2)(PPh(OEt)2)4]BF4](/Databaselist/images/loading.webp)
