benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Base Information

• Chemical Name: benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)
• CAS No.: 797057-61-5
• Molecular Formula: C₁₉H₂₄N₂O₂Pd
• Molecular Weight: 418.832
• Mol file: 797057-61-5.mol

Synonyms:

Chemical Property of benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

There total 1 articles about benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (82112-98-9) + silver benzoate (532-31-0) → benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (797057-61-5)

Guidance literature:

In acetone; under Ar; soln. of Pd complex in acetone added to Ag salt (molar ratio 1:1.1); stirred for 1 h in absence of light; filtered through Celite; filtrate concd. in vac.; pentane added; solid isolated; washed with pentane; dried in vac.; elem. anal.;

DOI:10.1021/om040061w

Reference yield:

benzoato(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II) (797057-61-5) + phenyl(trimethylsilylethynyl)iodonium triflate (133816-00-9) → Pd(benzoato)(triflato)(C2SiMe3)(2,6-(dimethylaminomethyl)phenyl-N,C,N) (907606-21-7)

Guidance literature:

In [⁽²⁾H₆]acetone; phenyl((trimethylsilyl)ethynyl)iodonium triflate added to a soln. of Pd complex at -50°C under Ar, kept at -80°C for 1 wk; not isolated, detected by NMR;

DOI:10.1021/om0601495

upstream raw materials:

chloro(2,6-bis(dimethylaminomethyl)phenyl-N,C,N)palladium(II)

silver benzoate

Downstream raw materials:

Pd(benzoato)(triflato)(C₂SiMe₃)(2,6-(dimethylaminomethyl)phenyl-N,C,N)