3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene

Base Information

• Chemical Name: 3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene
• CAS No.: 409360-04-9
• Molecular Formula: C₂₁H₄₀O₃SiSn
• Molecular Weight: 487.342
• Mol file: 409360-04-9.mol

Synonyms:

Chemical Property of 3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of 3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene

There total 1 articles about 3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 61.0%

trimethyltin(IV)chloride (1066-45-1) + 2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene (409360-03-8) → 3,5-dimethoxy-2-trimethylstannanyl-1-triisopropylsiloxymethylbenzene (409360-04-9)

Guidance literature:

With n-butyllithium; In tetrahydrofuran; to a soln. of Br-contg. compd. (12.4 mmol) in THF was added n-BuLi (24.4mmol) at -78°C ; stirring for 1 h; Sn-contg. compd. (62 mmol) in THF was added slowly; the soln. was allowed to warm up to room temp. ov ernight; under N2; THF was removed in vac. and replaced with ether; the ether phase was washed with satd. KF soln. and with water; ether was removed; recrystn. from hexane-ether; elem. anal.;

upstream raw materials:

trimethyltin(IV)chloride

2-bromo-3,5-dimethoxy-1-triisopropylsiloxymethylbenzene