Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane)

Base Information

Chemical Name:Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane)
CAS No.:379262-18-7
Molecular Formula:C₃₂H₄₂NiP₂S₂Si₂
Molecular Weight:667.626
Hs Code.:

Ni(SSiMe<sub>3</sub>)2(1,2-diphenylphosphino)ethane)

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Chemical Property of Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane)

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Technology Process of Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane)

There total 2 articles about Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 3574-04-7
hexamethylcyclotrisilathiane

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 917-54-4
methyllithium

: 379262-18-7
Ni(SSiMe₃)2(1,2-diphenylphosphino)ethane)

Guidance literature:: In tetrahydrofuran; diethyl ether; under inert atm. soln. (Me2SiS)3 in Et2O was treated with soln. MeLi in Et2O, stirred at 0°C for 5 min, and added to suspn. NiCl2(dppe) in THF and stirred at 0°C for 10 min, THF was added and stirred at0°C for 15 min; soln. was evapd., residue was extd. with toluene and centrifuged, soln. was concd., hexane was added, ppt. was filtered and washed with hexane; elem. anal.;
DOI:10.1039/b316567a

Reference yield: 87.0%

: 14647-23-5
1,2-bis(diphenylphosphino)ethane nickel(II) chloride

: 87495-22-5
sodium trimethylsilanethiolate

: 379262-18-7
Ni(dppe)(SSiMe₃)2

Guidance literature:: In tetrahydrofuran; (N2); standard air-sensitive technique; NaSSiMe3 (2.2 equiv.) was added to stirred suspn. of Ni complex in THF; suspn. was stirred for 20 min; solvent removed (vac.); extd. (ether); filtered through Celite; hexane added; crystd. (-30°C); elem. anal.;
DOI:10.1021/om010477z

Reference yield: 71.0%

: 75-09-2
dichloromethane

: 379262-18-7
Ni(dppe)(SSiMe₃)2

: [N(n-Bu)4][Ru(N)Cl₂Me₂]

: (Ni(dppe))(μ3-S)2(Ru(N)Me2)2*1/3CH2Cl2

Guidance literature:: In dichloromethane; under N2 atm. soln. Ni(dppe)(SSiMe3)2 in CH2Cl2 was added slowly at -30°C to soln. (Bu4N)(Ru(N)Cl2Me2) in CH2Cl2 and stirred at -30°C for 12 h; soln. was concd. in vacuo, chromy. on silica (hexane-CH2Cl2 4:1); elem. anal.;
DOI:10.1021/om034373v