rac-Cycloheptane-1β*,2α*-diol

Base Information

• Chemical Name: rac-Cycloheptane-1β*,2α*-diol
• CAS No.: 90970-69-7
• Molecular Formula: C₇H₁₄O₂
• Molecular Weight: 130.187
• Mol file: 90970-69-7.mol

Synonyms:

Chemical Property of rac-Cycloheptane-1β*,2α*-diol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of rac-Cycloheptane-1β*,2α*-diol

There total 47 articles about rac-Cycloheptane-1β*,2α*-diol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

Cycloheptene (628-92-2,45509-99-7) → cis-Cycloheptan-1,2-diol (13553-19-0,65678-03-7,90970-69-7,108268-27-5,108268-28-6,42114-72-7)

Guidance literature:

With potassium permanganate; dihydrogen peroxide; In water; acetone; at 0 ℃; for 2h; Temperature; Inert atmosphere; Green chemistry;

DOI:10.1039/c5ra01646k

Reference yield: 85.0%

cycloheptane (291-64-5) → cis-Cycloheptan-1,2-diol (13553-19-0,65678-03-7,90970-69-7,108268-27-5,108268-28-6,42114-72-7)

Guidance literature:

cycloheptane; With peracetic acid; sodium azide; 4-tolyl iodide; iodine; acetic acid; at 20 ℃; for 24h;

With lithium hydroxide; In methanol; at 20 ℃;

DOI:10.1039/C6SC03055F

Reference yield: 80.0%

8-oxabicyclo[5.1.0]octane (286-45-3) → (1S,2S)-cycloheptane-1,2-diol (13553-19-0,42114-72-7,65678-03-7,90970-69-7,108268-28-6,108268-27-5)

Guidance literature:

With potassium hydroxide; water; In dimethyl sulfoxide; at 100 - 110 ℃; for 3h;

DOI:10.1246/bcsj.53.2895

upstream raw materials:

Cycloheptene

silver(I) acetate

8-oxabicyclo[5.1.0]octane

iodine

Downstream raw materials:

heptanedioic acid

[(1R,2R)-2-((E)-Styryl)-cyclohexyl]-acetic acid (1R,2R)-2-hydroxy-cycloheptyl ester

pimelaldehyde

cis-1,2-diaminocycloheptane

Refernces

• 1、 Corti, Marco,Chiara, Rossella,Romani, Lidia,Mannucci, Barbara,Malavasi, Lorenzo,Quadrelli, Paolo. "g-C3N4/metal halide perovskite composites as photocatalysts for singlet oxygen generation processes for the preparation of various oxidized synthons". . p. 2292 - 2298. Retrieved 2021/04/12.
• 2、 Cancino, Patricio,Santiba?ez, Luis,Stevens, Christian,Fuentealba, Pablo,Audebrand, Nathalie,Aravena, Daniel,Torres, Julia,Martinez, Sebastian,Kremer, Carlos,Spodine, Evgenia. "Influence of the channel size of isostructural 3d-4f MOFs on the catalytic aerobic oxidation of cycloalkenes". supporting information. p. 11057 - 11064. Retrieved 2019/07/31.