bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate

Base Information

• Chemical Name: bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate
• CAS No.: 81646-41-5
• Molecular Formula: C₅₀H₄₅Cl₂P₄Pt₂*F₆P
• Molecular Weight: 1375.83
• Mol file: 81646-41-5.mol

Synonyms:

Chemical Property of bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate

There total 4 articles about bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

bis-μ-bis(diphenylphosphino)methane-μ-chloro-bis-[hydridoplatinum(II)] hexaflurophosphate (106228-77-7,81533-22-4,63872-42-4) → bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate (81646-41-5,63872-44-6)

Guidance literature:

With tetrachloromethane; In tetrachloromethane; 65°C;

DOI:10.1016/S0020-1693(00)94726-1

Reference yield:

bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[hydridoplatinum(II)] hexafluorophosphate (63911-00-2) → bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate (81646-41-5,63872-44-6)

Guidance literature:

With tetrachloromethane; In chloroform; N2-atmosphere; refluxing of Pt-complex soln. with few drops of CCl4 (1.5h); crystn. on cooling, filtration, washing (CHCl3), dissoln. in CH2Cl2, pptn. on MeOH addn., filtration, washing (MeOH), drying (vac.); elem. anal.;

DOI:10.1039/DT9780000516

Reference yield:

ammonium hexafluorophosphate + dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I) (61250-65-5) → bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] hexaflurophosphate (81646-41-5,63872-44-6)

Guidance literature:

With hydrogenchloride; In methanol; chloroform; addn. of 5 drops of concd. HCl to Pt-complex soln. (in CHCl3), addn. of NH4PF6 (in MeOH); evapn., washing (H2O), drying (vac.), recrystn. (CH2Cl2/MeOH);

DOI:10.1039/DT9780000516

upstream raw materials:

dichlorobis(bis(diphenylphosphino)methane)dichloroplatinum(I)

bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[hydridoplatinum(II)] hexafluorophosphate

bis-μ-bis(diphenylphosphino)methane-μ-hydrido-bis-[chloroplatinum(II)] chloride

bis-μ-bis(diphenylphosphino)methane-μ-chloro-bis-[hydridoplatinum(II)] hexaflurophosphate