tris(2,4,6-triisopropylphenyl)triphosphirane

Base Information

• Chemical Name: tris(2,4,6-triisopropylphenyl)triphosphirane
• CAS No.: 112790-12-2
• Molecular Formula: C₄₅H₆₉P₃
• Molecular Weight: 702.964
• Mol file: 112790-12-2.mol

Synonyms:

Chemical Property of tris(2,4,6-triisopropylphenyl)triphosphirane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tris(2,4,6-triisopropylphenyl)triphosphirane

There total 27 articles about tris(2,4,6-triisopropylphenyl)triphosphirane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 47.0%

dichloro(2,4,6-tri-isopropylphenyl)phosphane (53356-73-3) → tris(2,4,6-triisopropylphenyl)triphosphirane (112790-12-2,87437-17-0)

Guidance literature:

With zinc; trimethylphosphane; In tetrahydrofuran; at 20 ℃; for 16h; Reagent/catalyst;

DOI:10.1039/c9sc02322d

Reference yield: 18.0%

yttrium(III) iodide*3THF + C53H74OP2(2-)*2.5C4H10O2*2K(1+) → C61H90IO3P2Y + tris(2,4,6-triisopropylphenyl)triphosphirane (112790-12-2,87437-17-0)

Guidance literature:

In tetrahydrofuran; at 24 ℃; for 72h; Glovebox; Inert atmosphere;

DOI:10.1002/ejic.201700430

Reference yield:

dibromo(2,4,6-triisopropylphenyl)phosphane (87437-11-4) → C30H46Br2P2 + C60H92P4 + tris(2,4,6-triisopropylphenyl)triphosphirane (112790-12-2,87437-17-0)

Guidance literature:

With zinc; trimethylphosphane; In tetrahydrofuran; at 20 ℃; for 3h; Inert atmosphere; Darkness;

DOI:10.1039/d1dt03095g

upstream raw materials:

Dichlorodiphenylmethane

2,4,6-tri-isopropylphenyldilithiophosphide

dichloro(2,4,6-tri-isopropylphenyl)phosphane

2,4,6-tri-t-butylphenylphosphonous dichloride