Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester

Base Information

Chemical Name:Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester
CAS No.:56281-53-9
Molecular Formula:C₁₃H₁₇NS₂
Molecular Weight:251.417
Hs Code.:

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Chemical Property of Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester

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Technology Process of Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester

There total 1 articles about Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 20821-66-3
allyl N,N-dimethyldithiocarbamate

: 100-39-0
benzyl bromide

: 56281-53-9
Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester

Guidance literature:: Multistep reaction; (i) LDA, (ii) /BRN= 385801/;
DOI:10.1016/S0040-4039(01)91984-7

Reference yield: 52.0%

: 4226-01-1
tri-n-butyltin lithium

: 56281-53-9
Dimethyl-dithiocarbamic acid 1-benzyl-allyl ester

: 75950-62-8
PhCH₂CHCHCH₂(tributylstannyl)

Guidance literature:: With copper(I) bromide; In tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; addn. of a soln. of tributylstannyllithium in THF to a mixt. of the S-crotyl dithiocarbamate and CuBr in THF/HMPT at 0°C under Ar with stirring for 1 h; quenching with phosphate buffer soln. (pH 7), extn. with CH2Cl2, drying over Na2SO4, concg. under reduced pressure, chromy. on silica gel (hexane), IR, NMR;
DOI:10.1246/cl.1987.1967