2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide

Base Information

• Chemical Name: 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide
• CAS No.: 67889-22-9
• Molecular Formula: C₁₅H₁₂O₄S
• Molecular Weight: 288.324
• Mol file: 67889-22-9.mol

Synonyms:

Chemical Property of 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide

There total 1 articles about 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

→ 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide (67889-22-9)

Guidance literature:

Diester 5, NaOH/MeOH;

DOI:10.1016/S0040-4039(01)94689-1

Reference yield:

2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide (67889-22-9) → 2-(hydroxymethyl)-2'-<(methylamino)methyl>diphenyl sulfide (100695-83-8)

Guidance literature:

Multi-step reaction with 3 steps

1: SOCl₂ / 2 h / Heating

2: diethyl ether / 2 h

3: 1) PCl₅, 2)LiAlH₄ / 1) benzene, reflux, 1 h, 2) THF, 0 deg C, 30 min, then r.t., 35 h

With lithium aluminium tetrahydride; thionyl chloride; phosphorus pentachloride; In diethyl ether;

DOI:10.1246/bcsj.58.1946

Reference yield:

2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide (67889-22-9) → 2-(N-methylcarbamoyl)phenyl 2-(methoxycarbonyl)phenyl sulfide (100695-82-7)

Guidance literature:

Multi-step reaction with 2 steps

1: SOCl₂ / 2 h / Heating

2: diethyl ether / 2 h

With thionyl chloride; In diethyl ether;

DOI:10.1246/bcsj.58.1946

Downstream raw materials:

2-(2-Chlorocarbonyl-phenylsulfanyl)-benzoic acid methyl ester

2-(hydroxymethyl)-2'-<(methylamino)methyl>diphenyl sulfide

2-(N-methylcarbamoyl)phenyl 2-(methoxycarbonyl)phenyl sulfide