100695-82-7

Usage

Structure

Two aromatic rings
The compound has two benzene rings (aromatic rings) in its structure, which are connected by a sulfur atom.

Substitution

Methylcarbamoyl and methoxycarbonyl groups
One aromatic ring is substituted with a methylcarbamoyl group (NHCOCH3), and the other is substituted with a methoxycarbonyl group (OCH3).

Type of compound

Sulfur derivative
The compound is a derivative of sulfur, which is a chalcogen element, and plays a crucial role in the structure and reactivity of the molecule.

Potential applications

Organic synthesis and pharmaceutical research
Due to its unique structural features and potential reactivity, the compound may have applications in the fields of organic synthesis and pharmaceutical research.

Need for further research

Properties and potential uses
More research is required to fully understand the properties and potential uses of 2-(N-methylcarbamoyl)phenyl 2-(methoxycarbonyl)phenyl sulfide.

Upstream product

• 100695-81-6 2-(2-Chlorocarbonyl-phenylsulfanyl)-benzoic acid methyl ester 
• 74-89-5 methylamine 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 20054-45-9 N-methyl-2-sulfanylbenzamide 
• 67889-22-9 2-(methoxycarbonyl)phenyl 2-carboxyphenyl sulfide 
• 2527-58-4 2,2'-dithiobis(N-methylbenzamide) 
• 19602-82-5 2,2'-dithiodibenzoic acid dichloride 
• 119-80-2 2,2'-dithiobenzoic acid 

Downstream Products

• 100695-83-8 2-(hydroxymethyl)-2'-<(methylamino)methyl>diphenyl sulfide 

Relevant academic research and scientific papers

Structure and mechanism of hydrolysis of diaryl(acylamino)(chloro)-λ4-sulfanes and diaryl(acylamino)sulfonium salts

Aryl (methylaminocarbonylaryl) sulfides were converted by t-BuOCl to diaryl(acylamino)(chloro)-λ4-sulfanes or the corresponding diaryl(acylamino)sulfonium chlorides depending on the substituent of the S-aryl group. 1H NMR data showed that chloro-λ4-sulfanes exist only in CDCl3 and DMSO-d6 solvents, whereas in CD3OD complete ionic dissociation takes place, leading to sulfonium chlorides. Both the chemical shifts of 1H NMR signals and NOE data suggest that chloro-λ4-sulfanes and sulfonium salts having an o-MeO, o-Cl or o-Me substituent on the phenyl ring assume a skew conformation, whereas the aryl ring in compounds without an ortho-substituent can rotate practically free about the S-C(1') axis. In o-MeO-substituted derivatives there exists an equatorial 1,4 type S...O close contact. Sulfonium salts with axial 1,5 type S...O close contacts involving neighbouring COOMe, CONHMe, COMe or NO2 groups occur in butterfly conformation, like spiro-λ4-sulfanes. There is a correlation between the 15N chemical shift of the amide-nitrogen and the elongation of the S-N covalent bond, by which the interdepending S-N, S-Cl and S...O bonds can be characterized. Effective intermolecular S...O interaction was detected between the sulfonium centre and solvent molecules having a negatively polarized oxygen atom. The hydrolysis of sulfonium salts yielding sulfoxides was investigated by a kinetic method in 98:2 (v/v) dioxane-water mixture and in water. On the basis of medium, substituent (ρ + 1.03), steric, salt and kinetic isotope effects detailed mechanisms involving a hydroxy-λ4-sulfane intrmediate are proposed. The more reactive sulfonium salts with a five-membered hetero ring are hydrolyzed by water, whereas the sulfonium centre of the less reactive analogues with a six-membered ring is attacked only by OH- ions.

Alkylation and Oxidation of 6,7-Dihydro-6-methyl-5H-dibenzothiazocine. Selective Oxidation of the Sulfide Moiety by Transannular Participation of the Amino Group

6,7-Dihydro-6-methyl-5H-dibenzothiazocine (7) was prepared by cyclization of the corresponding amino alcohol using thionyl chloride in acetonitrile.Methylation of 7 gave N,N-dimethyl derivative (8) as the sole product.Treatment of 7 with various