bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)

Base Information

Chemical Name:bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)
CAS No.:177019-12-4
Molecular Formula:C₃₁H₄₄Mo₂N₂O₈P₂S₆
Molecular Weight:1018.92
Hs Code.:

Synonyms:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)

Chemical Property:

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Technology Process of bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)

There total 2 articles about bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

: 220390-06-7,103383-36-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-S)]

: 937-14-4
3-chloro-benzenecarboperoxoic acid

: 176799-53-4,176897-18-0,176897-19-1,176897-20-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO)]

: 176799-54-5,177019-12-4
bis(p-tolylimido)-bis(diethyl dithiophosphato)-(μ-acetato)-dimolybdenum(V)-(μ-SBn)-(μ-SO2)

Guidance literature:: With HBF₄; acetic acid; In acetone; byproducts: ClC6H4COOH; to chilled in ice-bath soln. Mo complex in acetone were added dropwise AcOH, 48 aq. HBF4 and chilled soln. m-ClC6H4CO3H in acetone, stirred for 3 min, aq. soln. NaHCO3 was added, stirred for 5 min, ppt. was filtered and washed with acetone-water; chromy. on silica (CH2Cl2);
DOI:10.1021/ic9002093

Reference yield: 84.0%

: 79-21-0
peracetic acid

: 220390-06-7,103383-36-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-S)]

: 177019-12-4,176799-54-5
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO2)]

Guidance literature:: In tetrahydrofuran; byproducts: AcOH; under red light; excess oxidant, stirring for 1 min; pptn. with 50% aq. EtOH, collection (filtration), drying (vac.);
DOI:10.1021/ic951518k

Reference yield: 85.0%

: 177019-12-4,176799-54-5
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-SO2)]

: 220390-06-7,103383-36-4
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-S)]

: 176698-33-2,176778-48-6
[Mo2(N-p-tolyl)2(S2P(OEt)2)2(μ-SCH2Ph)(μ-O)]

Guidance literature:: In chloroform; Irradiation (UV/VIS); 20-W white fluorescent lamps, 1.5 h; evapn. (reduced pressure), dissoln. in CHCl3, chromy. (SiO2, CHCl3), dissoln. in CH2Cl2, addn. of dodecane, standing for 2 d (pptn.), collection(filtration), washing (dodecane), drying (vac.);
DOI:10.1021/ic951518k