cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II)

Base Information

• Chemical Name: cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II)
• CAS No.: 92471-75-5
• Molecular Formula: C₄₀H₂₆Cl₂F₁₂P₂Pt
• Molecular Weight: 1062.56
• Mol file: 92471-75-5.mol

Synonyms:

Chemical Property of cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II)

There total 1 articles about cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

potassium tetrachloroplatinate(II) (10025-99-7) + Phenylbis<3-(trifluormethyl)phenyl>phosphan (747-86-4) → cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II) (92471-75-5,92451-55-3)

Guidance literature:

In ethanol; water; addn. of aq. soln. of K2(PtCl4) to hot ethanolic soln. of phosphane; stirring at room temp. for 24 h; filtering, washing with water, ethanol and ether, drying in vac. at room temp.; elem. anal.;

Reference yield: 63.0%

cis-dichlorobis{phenylbis(3-(trifluoromethyl)phenyl)phosphane}platinum(II) (92471-75-5,92451-55-3) + 4-methoxyphenyl magnesium bromide (13139-86-1) → cis-bis(4-methoxyphenyl)bis(phenylbis{3-(trifluoromethyl)phenyl}phosphane)platinum(II)

Guidance literature:

In tetrahydrofuran; benzene; dropping of soln. of Grignard reagent with vigorous stirring to suspn. (in abs. benzene) of Pt complex at 0°C; stirring at room temp. for 1 h; hydrolysing with ice water, sepg., extg. of aq. layer with C6H6 then CH2Cl2, washing with H2O, drying over MgSO4, evapg. to dryness, dissolving in CH2Cl2 then pptg. with n-hexane; elem. anal.;

upstream raw materials:

potassium tetrachloroplatinate(II)

Phenylbis<3-(trifluormethyl)phenyl>phosphan