triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

Base Information

Chemical Name:triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4
CAS No.:586956-45-8
Molecular Formula:C₃₇H₃₈N₄O₄SnW
Molecular Weight:905.293
Hs Code.:

triphenylstannyl-CH(3,5-Me<sub>2</sub>-4-EtPz)2W(carbonyl)4

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Chemical Property of triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

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Technology Process of triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

There total 2 articles about triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 34.0%

: 14040-11-0
tungsten hexacarbonyl

: 75-09-2
dichloromethane

: 586956-22-1
Ph₃SnCH(3,5-Me₂-4-EtPz)2

: 586956-45-8
triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

: [CH(3,5-Me2-4-EtPz)2-κ3-[N,C,N]]W(carbonyl)3(triphenylstannyl)*0.25CH2Cl2

Guidance literature:: With THF; Irradiation (UV/VIS); under Ar; ligand added to soln. of W(CO)5THF in THF, prepd. in situ by the irradn. of soln. of W(CO)6 in THF for 8 h; mixt. stirred and heated at reflux for 2 h; solvent removed under reduced pressure; residual solid purified by column chromy. (alumina, CH2Cl2/hexane (1:2 v/v)); elem. anal.;
DOI:10.1021/om030221o

Reference yield:

: 14040-11-0
tungsten hexacarbonyl

: 586956-22-1
Ph₃SnCH(3,5-Me₂-4-EtPz)2

: 586956-45-8
triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

: [CH(3,5-Me2-4-EtPz)2-κ3-[N,C,N]]W(carbonyl)3(triphenylstannyl)*0.25CH2Cl2

Guidance literature:: In 1,4-dioxane; under Ar; react. of the ligand with W(CO)6 in dioxane at reflux for 12 h;
DOI:10.1021/om030221o

Reference yield:

: 586956-45-8
triphenylstannyl-CH(3,5-Me₂-4-EtPz)2W(carbonyl)4

: 586956-44-7
[CH(3,5-Me2-4-EtPz)2-κ3-[N,C,N]]W(carbonyl)3(triphenylstannyl)

Guidance literature:: In chloroform-d1; under Ar; soln. of the complex in CDCl3 heated at 60 °C for 30 min; cooling to room temp.; not isolated; NMR;
DOI:10.1021/om030221o