fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Base Information

Chemical Name:fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]
CAS No.:1354037-28-7
Molecular Formula:C₃₂H₁₂BF₂₄*C₅₁H₅₃OP₃Rh
Molecular Weight:1741.03
Hs Code.:

Synonyms:

Suppliers and Price of fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

There total 1 articles about fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

: 1033128-87-8
[Rh(η6-C6H5F)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 166330-10-5
bis[2-(diphenylphosphino)phenyl] ether

: 1354037-28-7
fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In dichloromethane; byproducts: C6H5F; (Ar); using Schlenk techniques; addn. of DREphos to soln. of Rh(η6-C6H5F)(PCyp2(η5-C5H7))(B(C6H3(CF3)2)4) in CH2Cl2, stirring for 2 h; removal of solvent in vac., washing with pentane, drying under reduced pressure, diffusion of pentane into soln. in C6H5F, crystn.; elem. anal.;
DOI:10.1021/om201034m

Reference yield:

: 1354037-28-7
fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 1333-74-0
hydrogen

: fac-[RhH2(κ3-P,O,P-DPEphos)(tricyclopentylphosphine)][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In dichloromethane; (Ar); using Schlenk techniques; addn. of H2 (4 atm) to soln. of (Rh(O(C6H4PPh2)2)(P(C5H9)2C5H7))(B(C6H3(CF3)2)4) in CH2Cl2 for 10 min at 298 K;
DOI:10.1021/om201034m

Reference yield:

: 1354037-28-7
fac-[Rh(κ3-P,O,P-DPEphos)(P(cyclopentyl)2(η2-C5H7))][B(C6H3-3,5-(CF3)2)4]

: 1333-74-0
hydrogen

: 1354037-50-5
[Rh(κ3-P,O,P-DREphos)(tricyclopentylphosphine)][B(C6H3-3,5-(CF3)2)4]

Guidance literature:: In fluorobenzene; (Ar); using Schlenk techniques; freezing of fluorobenzene soln. of (Rh(O(C6H4PPh2)2)(P(C5H9)2C5H7))(B(C6H3(CF3)2)4) in liq. N2, placing under vac., filling with H2, shaking for 10 min, removal of H2 under vac. by freeze/pump/thaw of soln. 3 times; addn. of 3,3-dimethylbut-1-ene, removal of solvent under reduced pressure, washing with pentane, drying in vac.;
DOI:10.1021/om201034m