trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅)

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Chemical Name:trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅)
CAS No.:464896-38-6
Molecular Formula:C₉₆H₉₆F₁₀P₄Pt₂
Molecular Weight:1953.86
Hs Code.:
Mol file:464896-38-6.mol

trans,trans-(C<sub>6</sub>F<sub>5</sub>)(Ph<sub>2</sub>P)2(CH<sub>2</sub>)14Pt(C<sub>2</sub>)4Pt(CH<sub>2</sub>)14(Ph<sub>2</sub>P)2(C<sub>6</sub>F<sub>5</sub>)

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Chemical Property of trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅) Edit

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Technology Process of trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅)

There total 6 articles about trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: trans,trans-(C₆F₅)((p-tolyl)3P)2Pt(CC)4Pt(P(p-tolyl)3)2(C₆F₅)

: 76734-33-3
(C₆H₅)2P(CH₂)14P(C₆H₅)2

: 464896-38-6,464896-36-4
trans,trans-(C₆F₅)(Ph₂P-(CH₂)14PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)14Ph₂P-)(C₆F₅)

Guidance literature:: In dichloromethane; treated with phosphane in moderate dilute conditions;
DOI:10.1002/1521-3773(20020603)41:11<1871::AID-ANIE1871>3.0.CO;2-V

Reference yield: 84.0%

: 945679-67-4
trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4H

: 464896-36-4,464896-38-6
trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅)

Guidance literature:: With catalyst: CuI/N,N,N',N'-tetramethylethylenediamine; O₂; In acetone; a Schlenk flask was charged with CuCl and acetone, TMEDA was added with stirring, after 0.5 h of stirring O2 was bubbled, the soln. was heated to 65°C and added in portions over 1.5 h to a soln. of Pt-complex in acetone, 0.5 h; the solvent was removed, toluene was added, passed through an alumina column (toluene), the solvent was rotary evapd. and oil pump vac.; elem. anal.;
DOI:10.1021/ja071612n

Reference yield: 32.0%

: 464896-27-3
trans,trans-(C₆F₅)(Ph₂P(CH₂)6CH=CH₂)2Pt(C₂)4Pt(Ph₂P(CH₂)6CHCH₂)2(C₆F₅)

: 1333-74-0
hydrogen

: 464896-38-6,464896-36-4
trans,trans-(C₆F₅)(Ph₂P-(CH₂)14PPh₂)Pt-(C₂)4Pt-(Ph₂P(CH₂)14Ph₂P-)(C₆F₅)

: 464896-36-4,464896-38-6
trans,trans-(C₆F₅)(Ph₂P)2(CH₂)14Pt(C₂)4Pt(CH₂)14(Ph₂P)2(C₆F₅)

Guidance literature:: With catalyst: Pd/C; Grubbs catalyst first generation; In ethanol; 1,2-dichloro-ethane; 1. 5-7% Crubbs'catalyst, Pd-complex and CH2Cl2, reflux for 5 h, chromd. on alumina column (CH2Cl2), rotary evapd.; 2. the crude mixt., 10% Pd/C,ClCH2CH2Cl2, ethanol, 1 atm. of H2, stirred for 7 d; the solvent was rotary evapd., the CH2Cl2-soln. was passed through an alumina column (CH2Cl2), rotary evapd., preparative TLC (silica gel, 60:40v/v hexanes/CH2Cl2);
DOI:10.1021/ja071612n