N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine

Base Information

• Chemical Name: N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine
• CAS No.: 616895-33-1
• Molecular Formula: C₂₆H₁₈Cl₂N₂
• Molecular Weight: 429.348
• Mol file: 616895-33-1.mol

Synonyms:

Chemical Property of N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine

There total 1 articles about N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

3-chloro-aniline (108-42-9) + benzil (134-81-6) → N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine (616895-33-1)

Guidance literature:

In ethanol; for 24h; Reflux;

DOI:10.1016/j.bmcl.2009.03.078

Reference yield: 85.0%

nickel(II) bromide dimethoxyethane (28923-39-9) + N,N'-bis-(4-methoxybenzylidene)benzene-1,2-diimine (616895-33-1) → [((ClC6H4N)2C(C6H5)C(C6H5))NiBr2] (616895-47-7)

Guidance literature:

In tetrahydrofuran; under Ar atm., to soln. of ligand was added Ni complex, mixt. was stirred for 8 h at room temp.; solvent was reduced, pptn. by addition of pentane, ppt. was washed with pentane several times, dried in vac.; MAS;

DOI:10.1016/S0020-1693(03)00084-7

upstream raw materials:

3-chloro-aniline

benzil

Downstream raw materials:

[((ClC₆H₄N)2C(C₆H₅)C(C₆H₅))NiBr₂]