(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Base Information

Chemical Name:(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate
CAS No.:359864-76-9
Molecular Formula:BF₄*C₂₆H₂₀N₇O₂Ru
Molecular Weight:650.365
Hs Code.:

Synonyms:

Suppliers and Price of (nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of (nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

There total 1 articles about (nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 88.0%

: 1148-79-4
2,2':6,2''-terpyridine

: 13826-83-0
ammonium tetrafluroborate

: 2569-57-5
2-(phenylazo)pyridine

: 10049-08-8,63767-78-2
ruthenium(III)chloride

: 7632-00-0
sodium nitrite

: 359864-76-9
(nitro-κN)[2-(phenyldiazenyl-κN2)pyridine-κN](2,2':6',2''-terpyridine-κ3N)ruthenium(II) tetrafluoroborate

Guidance literature:: With AgNO₃; In water; acetone; byproducts: AgCl; RuCl3, 2,2':6',2''-terpyridine gave trichloro(terpyridine)Ru(III); 2-(phenylazo)pyridine added; soln. intermediate Cl(2-(phenyldiazenyl)pyridine)(terpyridine)Ru(II) chloride, AgNO3 in Me2CO/H2O reflux 15 min; NaNO2 added; 1 h heated; NH4BF4 added; 5 d; filtered off; washed (cool H2O, Et2O); crystn. (MeOH:M2CO = 1:1 v/v);
DOI:10.1107/S0108270101007715