(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

Base Information

Chemical Name:(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)
CAS No.:828923-82-6
Molecular Formula:C₃₁H₃₄FeN₂O₅
Molecular Weight:570.468
Hs Code.:

(C<sub>5</sub>H<sub>5</sub>)Fe(C<sub>5</sub>H<sub>4</sub>CH<sub>2</sub>OC<sub>6</sub>H<sub>4</sub>CH<sub>2</sub>CH(CO<sub>2</sub>CH<sub>3</sub>)NHCH<sub>2</sub>CH<sub>2</sub>NHC(O)OCH<sub>2</sub>C<sub>6</sub>H<sub>5</sub>)

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Chemical Property of (C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

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Technology Process of (C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

There total 2 articles about (C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

: 828923-80-4,828923-78-0,828923-55-3
(D,L)-O-ferrocenylmethyl-tyrosine methyl ester

: 67561-03-9
N-benzyloxycarbonylglycinal

: 828923-82-6,828923-84-8,828923-56-4
(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

Guidance literature:: With sodium cyanoborohydride; zinc(II) chloride; In methanol; under N2; mixt. of ZnCl2 and NaCNBH3 in dry MeOH added slowly at 0°C into soln. of aminoacetaldehyde and Fe complex in dry MeOH; stirred at room temp. for 18 h; solvent evapd.; taken up with CH2Cl2; washed (aq. NaHCO3); aq. phase extd. (CH2Cl2); combined org. phase washed (H2O); dried (Na2SO4); evapd. invac.; column chromd. (silica gel, light petroleum-AcOEt 3:7);
DOI:10.1016/j.jorganchem.2004.09.049

Reference yield: 75.0%

: 1273-86-5
1-ferrocenylmethanol

: 2-(2-benzyloxycarbonylamino-ethylamino)-3-(4-hydroxy-phenyl)-propionic acid methyl ester

: 828923-82-6,828923-84-8,828923-56-4
(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

Guidance literature:: With triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; under N2; tyrosine derivative and PPh3 added at room temp. to soln. of Fe complex in dry THF; cooled to 0°C; THF soln. of DEAD added slowly; stirred at room temp. for 4 d; solvent evapd.; dissolved in CH2Cl2; washed with brine; aq. phase extd. (CH2Cl2); combined org. phase dried (Na2SO4); evapd.; purified by columnchromy. (silica gel, light petroleum-AcOEt 3:7);
DOI:10.1016/j.jorganchem.2004.09.049

Reference yield:

: 20924-05-4
thymidyl acetic acid

: 828923-82-6,828923-84-8,828923-56-4
(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)NHCH₂CH₂NHC(O)OCH₂C₆H₅)

: 828923-51-9,828923-86-0,828923-88-2
(C₅H₅)Fe(C₅H₄CH₂OC₆H₄CH₂CH(CO₂CH₃)N(CH₂CH₂NHC(O)OCH₂C₆H₅)C(O)CH₂N₂C₄H₂O₂CH₃)

Guidance literature:: With 3-hydroxy-3,4-dihydrobenzotriazine-4-one; dicyclohexyl-carbodiimide; In N,N-dimethyl-formamide; under N2; mixt. of DCC, carboxymethyl thymine and 3,4-dihydro-3-hydroxy-4-oxo-1,2,3-benzotriazine in dry DMF stirred (room temp., 1 h); soln. ofFe complex in DMF added; stirred (room temp., 20 h); filtered; solvent distd. off; taken up with AcOEt; washed (aq. NaHCO3); aq. phase extd. (AcOEt); combined org. phase washed (H2O); dried (Na2SO4); evapd.; column chromd. (silica gel, AcOEt-light petroleum 6:4); elem.anal.;
DOI:10.1016/j.jorganchem.2004.09.049