2-Me₃SnC₆F₄PPh₂

Base Information

• Chemical Name: 2-Me₃SnC₆F₄PPh₂
• CAS No.: 1192748-44-9
• Molecular Formula: C₂₁H₁₉F₄PSn
• Molecular Weight: 497.059
• Mol file: 1192748-44-9.mol

Synonyms:

Chemical Property of 2-Me₃SnC₆F₄PPh₂

Chemical Property:

Purity/Quality:

Safty Information:

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• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-Me₃SnC₆F₄PPh₂

There total 1 articles about 2-Me₃SnC₆F₄PPh₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

(2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine (27384-33-4) + trimethyltin(IV)chloride (1066-45-1) → 2-Me3SnC6F4PPh2 (1192748-44-9)

Guidance literature:

With n-BuLi; In diethyl ether; hexane; under Ar; soln. of BrC6F4PPh2 in ether cooled to -78°C; treated slowly with soln. of n-BuLi in hexanes; stirred for 30 min; Me3SnCl in hexanes added dropwise; stirred at -78°C for 2 h; warmed to room temp.; hydrolyzed; ether layer sepd.; aq. phase extd. with ether; combined org.phases dried (MgSO4); filtered; solvent removed; recrystd. from hot MeO H; elem. anal.;

DOI:10.1021/om200179v

Reference yield: 84.0%

(tetrahydrothiophene)gold(I) chloride (39929-21-0) + 2-Me3SnC6F4PPh2 (1192748-44-9) → [Au2I(μ-2-C6F4PPh2)2] (1192747-82-2)

Guidance literature:

In dichloromethane; Sn compd. added to a soln. of Au complex, refluxed for 4 h; evapd. (vac.), recrystd. (CH2Cl2/hexane);

DOI:10.1039/b906769h

Reference yield: 62.0%

bis(η3-allyl-μ-chloropalladium(II)) + 2-Me3SnC6F4PPh2 (1192748-44-9) → [Pd(allyl)(μ-2-C6F4PPh2)]2

Guidance literature:

In dichloromethane; Schlenk technique; Inert atmosphere;

DOI:10.1021/acs.inorgchem.7b00410

upstream raw materials:

(2-bromo-3,4,5,6-tetrafluorophenyl)diphenylphosphine

trimethyltin(IV)chloride

Downstream raw materials:

[Au₂^I(μ-2-C₆F₄PPh₂)₂]

cis-[Pd2(μ-Cl)2(κ2-2-C6F4PPh2)2]

trans-[Pd2(μ-Cl)2(κ2-2-C6F4PPh2)2]

cis-[Pd2(μ-Br)2(κ2-2-C6F4PPh2)2]