allyl 3-phenyl-3-trimethylstannylpropanoate

Base Information

Chemical Name:allyl 3-phenyl-3-trimethylstannylpropanoate
CAS No.:115872-67-8
Molecular Formula:C₁₅H₂₂O₂Sn
Molecular Weight:353.048
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of allyl 3-phenyl-3-trimethylstannylpropanoate

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Technology Process of allyl 3-phenyl-3-trimethylstannylpropanoate

There total 1 articles about allyl 3-phenyl-3-trimethylstannylpropanoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 56289-55-5,56289-56-6,1866-31-5
allyl cinnamate

: 17946-71-3
lithium trimethylstannyl

: 115872-67-8
allyl 3-phenyl-3-trimethylstannylpropanoate

Guidance literature:: In tetrahydrofuran; allyl cinnamate in THF is added dropwise during 20 min to stirred soln. of trimethylstannyl-lithium in THF at -78°C, methanol is added after 15 min, soln. is brought to room temp., water is added, mixt. is separated; aq. layer is extd. (ether), org. layers are washed (water, brine), drying (Na2SO4), chromy. (light petroleum-ethyl acetate);

Reference yield: 49.0%

: 115872-67-8
allyl 3-phenyl-3-trimethylstannylpropanoate

: 100-52-7
benzaldehyde

: (2SR,3SR)-allyl 2-{(RS)-1-hydroxybenzyl}-3-phenyl-3-trimethylstannylmethylpropanoate

: (2SR,3SR)-allyl 2-{(RS)-1-hydroxybenzyl}-3-phenyl-3-trimethylstannylmethylpropanoate

Guidance literature:: With ammonium chloride; lithium diisopropyl amide; In tetrahydrofuran; β-stannyl ester in THF is added dropwise during 5 min to stirred soln. of LDA in THF at -78°C, after 45 min aldehyde in THF is addeddropwise during 5 min, mixt. is kept at -78°C for 10 min, methanol and aq. ammonium chloride is added; mixt. is brought to room temp., water is added, extd. (ether), org. layers are washed (water, brine), dried (Na2SO4), evapd., chromy. (light petroleum-ethyl acetate);

Reference yield:

: 115872-67-8
allyl 3-phenyl-3-trimethylstannylpropanoate

: 75-07-0,9002-91-9
acetaldehyde

: (2SR,3SR)-allyl 3-hydroxy-2-{(SR)-1-phenyl-1-trimethylstannylmethyl}butanoate

: (2SR,3RS)-allyl 3-hydroxy-2-{(SR)-1-phenyl-1-trimethylstannylmethyl}butanoate

Guidance literature:: With ammonium chloride; lithium diisopropyl amide; In tetrahydrofuran; β-stannyl ester in THF is added dropwise during 5 min to stirred soln. of LDA in THF at -78°C, after 45 min aldehyde in THF is addeddropwise during 5 min, mixt. is kept at -78°C ffor 10 min, methanol and aq. ammonium chloride is added; mixt. is brought to room temp., water is added, extd. (ether), org. layers are washed (water, brine), dried (Na2SO4), evapd., chromy. (light petroleum-ethyl acetate), 77:23 mixt. of (2SR,3RS,1'SR)-ester and (2SR,3SR,1'SR)-ester (yield 70%);