(p-F₃CC₆H₄)3PAuSC₆H₅

Base Information

• Chemical Name: (p-F₃CC₆H₄)3PAuSC₆H₅
• CAS No.: 385815-86-1
• Molecular Formula: C₂₇H₁₇AuF₉PS
• Molecular Weight: 772.424
• Mol file: 385815-86-1.mol

Synonyms:

Chemical Property of (p-F₃CC₆H₄)3PAuSC₆H₅

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (p-F₃CC₆H₄)3PAuSC₆H₅

There total 2 articles about (p-F₃CC₆H₄)3PAuSC₆H₅ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

[tris(para(trifluoromethyl)phenyl)phosphine]gold(I) chloride (385815-83-8) + thiophenol (108-98-5) → (p-F3CC6H4)3PAuSC6H5 (385815-86-1)

Guidance literature:

With KOH; In dichloromethane; acetone; under N2 or Ar using Schlenk techniques; soln. of Au complex in CH2Cl2/acetone added to soln. of PhSH in MeOH and KOH; mixt stirred overnight atroom temp.; solvent removed; extd. (CH2Cl2); recrystd. (CH2Cl2/hexane); elem. anal.;

DOI:10.1016/S0020-1693(01)00543-6

Reference yield:

tris(para-trifluoromethyl)phenyl phosphine (13406-29-6) → (p-F3CC6H4)3PAuSC6H5 (385815-86-1)

Guidance literature:

Multi-step reaction with 2 steps

1: β-thiodiglucol / water; dichloromethane; methanol

2: KOH / dichloromethane; acetone

With β-thiodiglucol; KOH; In methanol; dichloromethane; water; acetone;

DOI:10.1016/S0020-1693(01)00543-6

Reference yield:

(p-F3CC6H4)3PAuSC6H5 (385815-86-1) + dimethyl acetylenedicarboxylate (762-42-5) → C33H23AuF9O4PS

Guidance literature:

With tris-p-methoxyphenylphosphine sulphide; In ⁽²⁾H₈-toluene; at -20 ℃; regioselective reaction; Glovebox;

DOI:10.1021/acs.organomet.5b00078

upstream raw materials:

[tris(para(trifluoromethyl)phenyl)phosphine]gold(I) chloride

thiophenol

tris(para-trifluoromethyl)phenyl phosphine