[Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

Base Information

• Chemical Name: [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]
• CAS No.: 1235583-81-9
• Molecular Formula: C₂₉H₃₂N₂O₂Pd
• Molecular Weight: 547.005

Synonyms:

Chemical Property of [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

There total 1 articles about [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

pyridine (110-86-1) + chloromethyl(1,5-cyclooctadiene)palladium(II) + 2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalenediolate sodium salt → [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] (1235583-81-9)

Guidance literature:

In toluene; addn. of pyridine to soln. of 2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene sodium salt in toluene, addn. of Pd(COD)MeCl, stirring at room temp. for 15 h; filtration by a syringe membrane, removal of solvent by vac.;

DOI:10.1021/om1003013

Reference yield:

norborn-2-ene (498-66-8) + [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] (1235583-81-9) + [13C]Carbon monoxide (1641-69-6) → [Pd(C7H10(13)COC7H10(13)COCH3)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] (1235583-92-2)

Guidance literature:

In benzene-d6; addn. of (13)CO (40 psi) to soln. of PdPy(HOC10H5(O)CHNC6H3(i-Pr)2)Me in C6D6 in NMR tube, release of unreacted (13)CO, addn. of norbornene (0.5 equiv.); addn. of (13)CO (40 psi) again, release of free (13)CO, addn.of 2 equiv. of norbornene; monitoring by NMR;

DOI:10.1021/om1003013

Reference yield:

norborn-2-ene (498-66-8) + [Pd(Me)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] (1235583-81-9) + [13C]Carbon monoxide (1641-69-6) → [Pd(C7H10(13)COCH3)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))] (1235583-90-0)

Guidance literature:

In benzene-d6; addn. of (13)CO (40 psi) to soln. of Pd(Py)(Me)(HOC10H5(O)CHNC6H3(i-Pr)2) in C6D6 in high-pressure NMR tube, release of unreacted (13)CO, addn.of norbornene (0.5 equiv.); monitoring by NMR;

DOI:10.1021/om1003013

upstream raw materials:

pyridine

Downstream raw materials:

[Pd(C₇H₁₀⁽¹³⁾COCH₃)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

[Pd(pyridine)(C₇H₁₀⁽¹³⁾COCH₃⁽¹³⁾CO)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

[Pd(C₇H₁₀⁽¹³⁾COC₇H₁₀⁽¹³⁾COCH₃)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

[Pd(⁽¹³⁾COCH₃)(pyridine)(2-(2,6-diisopropylphenyl)imino-1,8-dihydroxynaphthalene(-1H))]

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