[(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

Base Information

Chemical Name:[(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂
CAS No.:1005189-86-5
Molecular Formula:C₂₆H₃₂N₄Pd
Molecular Weight:506.987
Hs Code.:

[(1-Me-imidazol-2-yl)2CH(CH(4-MeC<sub>6</sub>H<sub>4</sub>)2)]PdMe<sub>2</sub>

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Chemical Property of [(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

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Technology Process of [(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

There total 1 articles about [(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

: dimethyl(pyridazine)palladium(II)

: 1005189-77-4
(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)

: 1005189-86-5
[(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

Guidance literature:: In diethyl ether; under N2; Et2O soln. of ligand added to Et2O suspn. of Pd complex; stirred at 25°C for 1 h; filtered; solid rinsed with Et2O; dissolved in CH2Cl2 at -78°C; warmed to 0°C; volatiles removed in vac.; washed with pentane; dried under vac.;
DOI:10.1021/om700768j

Reference yield:

: 74-85-1
ethene

: 1005189-86-5
[(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

: N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

: 1005190-21-5
[((1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2))PdMe(ethylene)][B(C₆F₅)4]

Guidance literature:: In dichloromethane-d2; byproducts: CH4; under N2; in NMR tube; CD2Cl2 added at -78°C to mixt. of Pd complex and (HNMe2Ph)B(C6F5)4; shaken at -78°C; cooled to -196°C; ethylene (ca. 4 equiv.) added; warmed to -78°C; not isolated; detd. by (1)H and (13)C NMR spectra;
DOI:10.1021/om700768j

Reference yield:

: 1005189-86-5
[(1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2)]PdMe₂

: 201230-82-2
carbon monoxide

: N,N'-dimethylaniliniumtetrakis(pentafluorophenyl)borate

: 1005190-09-9
[((1-Me-imidazol-2-yl)2CH(CH(4-MeC₆H₄)2))Pd(C(O)Me)(CO)][B(C₆F₅)4]

Guidance literature:: In dichloromethane-d2; byproducts: CH4; under N2; in NMR tube; CD2Cl2 added at -78°C to mixt. of Pd complex and (HNMe2Ph)B(C6F5)4; shaken at -78°C; cooled to -196°C; exposed to CO (5 atm); sealed; warmed to -78°C; briefly warmedto 0°C; shaken; not isolated; detd. by (1)H and (13)C NMR and IR spectra;
DOI:10.1021/om700768j