4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole

Base Information

Chemical Name:4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole
CAS No.:23731-63-7
Molecular Formula:C₁₂H₁₄O₄
Molecular Weight:222.241
Hs Code.:
DSSTox Substance ID:DTXSID301240046
Wikidata:Q105190211
Mol file:23731-63-7.mol

Synonyms:23731-63-7;4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole;DTXSID301240046;AKOS030241158;4,5-Dimethoxy-6-(1-propen-1-yl)-1,3-benzodioxole

Suppliers and Price of 4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
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Total 1 raw suppliers

Chemical Property of 4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole

Chemical Property:

XLogP3:2.7
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:3
Exact Mass:222.08920892
Heavy Atom Count:16
Complexity:253

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:CC=CC1=CC2=C(C(=C1OC)OC)OCO2

Technology Process of 4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole

There total 1 articles about 4,5-dimethoxy-6-(prop-1-en-1-yl)-2H-1,3-benzodioxole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 23731-63-7
4,5-dimethoxy-6-(prop-1-en-1-yl)benzo[1,3]dioxole

: 50915-44-1
5-allyl-3,4-dimethoxy-pyrocatechol

Guidance literature:: With potassium hydroxide;

Reference yield: 80.0%

: 23731-63-7
4,5-dimethoxy-6-(prop-1-en-1-yl)benzo[1,3]dioxole

: 23731-65-9
2,3-dimethoxy-4,5-methylenedioxybenzaldehyde

Guidance literature:: 4,5-dimethoxy-6-(prop-1-en-1-yl)benzo[1,3]dioxole; With ozone; In pyridine; methanol; chloroform; at -25 ℃;

With water;
DOI:10.1007/s11172-007-0389-1

Reference yield:

: 23731-63-7
4,5-dimethoxy-6-(prop-1-en-1-yl)benzo[1,3]dioxole

: 1293408-43-1
(3-hydroxy-4-methoxyphenyl)(2,3-dimethoxy-4,5-methylenedioxyphenyl)methanone

Guidance literature:: Multi-step reaction with 6 steps

1.1: pyridine; ozone / methanol; chloroform / -15 °C

2.1: urea hydrogen peroxide adduct; sodium hydroxide / methanol; water / 1.5 h / Reflux

3.1: acetonitrile / 0.33 h / 20 °C

4.1: triethylamine / acetonitrile / 20 h / 40 °C

5.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C / Inert atmosphere

5.2: 20 °C / Inert atmosphere

6.1: tetra-n-butylammoniumfluoride trihydrate / tetrahydrofuran / 1 h / 20 °C

With pyridine; n-butyllithium; urea hydrogen peroxide adduct; ozone; tetra-n-butylammoniumfluoride trihydrate; triethylamine; sodium hydroxide; In tetrahydrofuran; methanol; hexane; chloroform; water; acetonitrile;
DOI:10.1016/j.bmcl.2011.01.124