phenyl[tetrakis(2,2,2-trifluoroethoxy)]-lambda~5~-phosphane

Base Information

• Chemical Name: phenyl[tetrakis(2,2,2-trifluoroethoxy)]-lambda~5~-phosphane
• CAS No.: 63325-06-4
• Molecular Formula: C14H13 F12 O4 P
• Molecular Weight: 504.209
• Mol file: 63325-06-4.mol

Synonyms:

Chemical Property of phenyl[tetrakis(2,2,2-trifluoroethoxy)]-lambda~5~-phosphane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of phenyl[tetrakis(2,2,2-trifluoroethoxy)]-lambda~5~-phosphane

There total 3 articles about phenyl[tetrakis(2,2,2-trifluoroethoxy)]-lambda~5~-phosphane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

Phenylbis-(2,2,2-trifluorethoxy)-phosphin (55322-67-3) + 2,2,2-trifluoroethyl benzenesulfenate (76943-18-5) → phenyltetrakis(2,2,2-trifluoroethoxy)phosphorane (63325-06-4)

Guidance literature:

In pentane; for 1h; Ambient temperature;

DOI:10.1021/ja00397a033

Reference yield:

Dichlorophenylphosphine (644-97-3) → phenyltetrakis(2,2,2-trifluoroethoxy)phosphorane (63325-06-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 76 percent / triethylamine / tetrahydrofuran / -20 °C

2: 81 percent / pentane / 1 h / Ambient temperature

With triethylamine; In tetrahydrofuran; pentane;

DOI:10.1021/ja00397a033

Reference yield:

→ phenyltetrakis(2,2,2-trifluoroethoxy)phosphorane (63325-06-4)

Guidance literature:

DOI:10.1021/ic50175a026

upstream raw materials:

Phenylbis-(2,2,2-trifluorethoxy)-phosphin

2,2,2-trifluoroethyl benzenesulfenate

Dichlorophenylphosphine

Downstream raw materials:

2,2,2-trifluoroethanol

Phenyl-phosphonic acid bis-(2,2,2-trifluoro-ethyl) ester

C₁₂H₁₁F₁₀O₃P