[bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

Base Information

Chemical Name:[bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]
CAS No.:602298-02-2
Molecular Formula:C₃H₃I₃IrO₂*C₃₆H₃₀NP₂
Molecular Weight:1182.58
Hs Code.:

[bis(triphenylphosphoranylidene)ammonium][IrI<sub>3</sub>(CH<sub>3</sub>)(CO)2]

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Chemical Property of [bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

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Technology Process of [bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

There total 1 articles about [bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 153735-01-4,602298-00-0
cis-bis(triphenylphosphine)iminium diiododicarbonyliridium(I)

: 74-88-4
methyl iodide

: 602298-02-2
[bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

Guidance literature:: In dichloromethane; (inert atm.) CH3I was added to the soln. of complex in CH2Cl2, the mixt.was stirred at room temp. for 1 h; the solvent was removed under vac., crystd. from CH2Cl2/n-hexane (1/1); elem. anal.;
DOI:10.1021/om060282x

Reference yield: 75.0%

: 602298-02-2
[bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

: 201230-82-2
carbon monoxide

: 917704-02-0,917704-16-6
fac,cis-[PPN][Ir(COCH₃)I₃(CO)2]

Guidance literature:: In methanol; dichloromethane; High Pressure; (inert atm.) the soln. of complex in CH2Cl2 containing methanol was stirred for 90 min under 5 bar of CO at room temp.; n-hexane was added by a liquid feed line, the reactor was cooled to 0°C for 2 h;
DOI:10.1021/om060282x

Reference yield: 75.0%

: 602298-02-2
[bis(triphenylphosphoranylidene)ammonium][IrI₃(CH₃)(CO)2]

: 201230-82-2
carbon monoxide

: 917704-02-0,917704-16-6
mer,trans-[PPN][Ir(COCH₃)I₃(CO)2]

Guidance literature:: In methanol; High Pressure; (inert atm.) the soln. of complex in methanol was stirred for 1 h under 5 bar of CO at room temp.; n-hexane was added by a liquid feed line overpressurized with CO, the reactor was cooled to 0°C for 2 h;
DOI:10.1021/om060282x