Benzamide, 2-methoxy-N-1-propenyl-, (E)-

Base Information

Chemical Name:Benzamide, 2-methoxy-N-1-propenyl-, (E)-
CAS No.:139583-86-1
Molecular Formula:C₁₁H₁₃NO₂
Molecular Weight:191.23
Hs Code.:

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Chemical Property of Benzamide, 2-methoxy-N-1-propenyl-, (E)-

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Technology Process of Benzamide, 2-methoxy-N-1-propenyl-, (E)-

There total 1 articles about Benzamide, 2-methoxy-N-1-propenyl-, (E)- which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: 66897-24-3
o-methoxy-N-allylbenzamide

: 139583-86-1,139583-87-2
N-propenyl-o-methoxybenzamide

Guidance literature:: With lithium diisopropyl amide; In tetrahydrofuran; hexane; -70 deg C, 10 min, then to 0 deg C;
DOI:10.1021/jo00035a030

Reference yield:

: 139583-86-1,139583-87-2
N-propenyl-o-methoxybenzamide

: 6161-65-5
2-methoxy-6-methyl-benzoic acid

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) tert-butyllithium / 1.) THF, pentane, -100 deg C, 10 min , then to -70 deg C 2.) THF, to 0 deg C

2: 86 percent / 50 percent aq. acetic acid / 60 °C

3: 79 percent / HO₃SONO, H₂O / CH₂Cl₂ / Ambient temperature

With nitrosylsulfuric acid; water; tert.-butyl lithium; acetic acid; In dichloromethane;
DOI:10.1021/jo00035a030

Reference yield:

: 139583-86-1,139583-87-2
N-propenyl-o-methoxybenzamide

: 53005-44-0
2-methoxy-6-methyl-benzonitrile

Guidance literature:: Multi-step reaction with 3 steps

1: 1.) tert-butyllithium / 1.) THF, pentane, -100 deg C, 10 min , then to -70 deg C 2.) THF, to 0 deg C

2: 86 percent / 50 percent aq. acetic acid / 60 °C

3: 91 percent / trifluoroacetic anhydride, pyridine / CH₂Cl₂ / Ambient temperature

With pyridine; tert.-butyl lithium; acetic acid; trifluoroacetic anhydride; In dichloromethane;
DOI:10.1021/jo00035a030