(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

Base Information

Chemical Name:(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane
CAS No.:912806-53-2
Molecular Formula:C₅₁H₈₄Br₂Si₆Sn
Molecular Weight:1144.26
Hs Code.:

Synonyms:

Suppliers and Price of (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Total 2 raw suppliers

Chemical Property of (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

There total 1 articles about (2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 912806-60-1
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)stannane

: 7726-95-6
bromine

: 912806-53-2
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

Guidance literature:: In diethyl ether; under Ar; soln. of Sn compd. (0.74 mmol) and Br2 (0.84 mmol) in Et2O (40ml) stirred (room temp., 30 min); washed with satd. aq. soln. of Na2SO3 and then with satd. aq. soln. of NaCl; org. layer dried with Na2SO4; solvent removed; residue recrystd. from CHCl3 and EtOH; elem. anal.;
DOI:10.1002/ejic.200500375

Reference yield: 93.0%

: 861718-25-4
lithium naphthalene

: 912806-53-2
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

: 74-88-4
methyl iodide

: 912806-62-3
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dimethylstannane

Guidance literature:: In tetrahydrofuran; under Ar; 1.30 N soln. (0.15 ml) of LiC10H8 added to soln. of Sn compd. (39.8 μmol) (-78°C); stirred (-78°C, 1 h); MeI (1.6 mmol) added; solvent removed; hexane added; filtered; filtrate concd.; subjected to GPLC (CHCl3) and PTLC (hexane); elem. anal.;
DOI:10.1002/ejic.200500375

Reference yield: 8.0%

: 861718-25-4
lithium naphthalene

: 912806-53-2
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)dibromostannane

: 10025-71-5
tellurium dichloride

: 108-88-3,15644-74-3,16713-13-6
toluene

: 912806-56-5
2,2''-diisopropyl-1,1':3',1'-terphenyl

: 912806-55-4
(2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)2Te₂

: ((2,4,6-tris[bis(trimethylsilyl)methyl]phenyl)(2,2''-diisopropyl-1,1':3',1'-terphenyl)Sn)2Te₄Sn*1.5(toluene)

: 115134-77-5
2,4,6-tris(bis(trimethylsilyl)methyl)benzene

Guidance literature:: In tetrahydrofuran; under Ar; 1.24 N sol. (0.38 ml) of LiC10H8 added to soln. (1.0 ml) of Sncompd. (94.0 μmol) (-78°C); stirred (-78°C, 1 h); TeCl 2 (101 μmol) added; warmed to room temp. (10 h); solvent removed; hexane added; filtered; evapd.; residue subjected to GPLC (toluene); elem. anal.;
DOI:10.1002/ejic.200500375