[(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)]

Base Information

• Chemical Name: [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)]
• CAS No.: 1204766-55-1
• Molecular Formula: C₂₇H₁₃ClF₁₈N₂Ru
• Molecular Weight: 843.908
• Mol file: 1204766-55-1.mol

Synonyms:

Chemical Property of [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)]

There total 1 articles about [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

dichloro(benzene)ruthenium(II) dimer (37366-09-9) + Li((3,5-(CF3)2C6H3)NC(CF3))2CH → [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)] (1204766-55-1)

Guidance literature:

In dichloromethane; (N2); soln. of lithium complex in CH2Cl2 was added to ruthenium complex in CH2Cl2, stirred for 14 h; filtered through cellite, concd. in vac., precipitated with pentane, solid was collected, washed with pentane, crystd. from acetone (or CHCl3)/pentane, washed with pentane, dried in vac. for 10 h, elem. anal.;

DOI:10.1021/om900991b

Reference yield: 97.2%

trimethylsilyl trifluoromethanesulfonate (27607-77-8) + [(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)] (1204766-55-1) → [(η6-C6H6)Ru(OTf)(3,5-(CF3)2C6H3NC(CF3))2CH)] (1335025-10-9)

Guidance literature:

In dichloromethane; byproducts: Me3SiCl; (N2); std. Schlenk technique; Me3SiO3SCF3 was added within 5 min to soln. of Ru complex in degassed CH2Cl2; stirred for 2 h; evapd. (vac.); washed (degassed pentane); dried in vac. for 4 h; elem. anal.;

DOI:10.1021/om200566a

Reference yield: 60.0%

[(η6-C6H6)RuCl(3,5-(CF3)2C6H3NC(CF3))2CH)] (1204766-55-1) + sodium tetrakis[(3,5-di-trifluoromethyl)phenyl]borate (79060-88-1) → [(η6-C6H6)Ru(3,5-(CF3)2C6H3NC(CF3))2CH)](B(3,5-(CF3)2C6H3)4) (1335025-12-1)

Guidance literature:

In dichloromethane; byproducts: NaCl; (N2); std. Schlenk technique; soln. of Ru complex and Na salt (1.05 equiv.) in N2-satd. CH2Cl2 was stirred overnight; filtered over Celite; evapd. (vac.); washed (degassed pentane); dried (vac.); elem. anal.;

DOI:10.1021/om200566a

upstream raw materials:

dichloro(benzene)ruthenium(II) dimer

Downstream raw materials:

[(η6-C6H6)Ru(OTf)(3,5-(CF3)2C6H3NC(CF3))2CH)]

[(η6-C6H6)Ru(3,5-(CF3)2C6H3NC(CF3))2CH)](B(3,5-(CF3)2C6H3)4)