PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine)

Base Information

• Chemical Name: PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine)
• CAS No.: 1176917-20-6
• Molecular Formula: C₂₄H₁₇ClN₄O₄PdS
• Molecular Weight: 599.362
• Mol file: 1176917-20-6.mol

Synonyms:

Chemical Property of PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine)

There total 2 articles about PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

pyridine (110-86-1) + bis(benzo[h]quinolinato-C(12)N(1))(μ-chlorido)palladium(II) (31114-75-7,25794-30-3) + (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II) (1063716-38-0) → PdCl(N(C6H4NO2)C13H8N)(pyridine) (1176917-20-6,934201-66-8)

Guidance literature:

In tetrahydrofuran; at 23 ℃; for 17h;

Reference yield: 76.0%

pyridine (110-86-1) + di-μ-chlorobis{(7,7-benzoquinoline)palladium(II)} + [N-(nosyl)imino]phenyliodinane (149552-43-2) → PdCl(N(C6H4NO2)C13H8N)(pyridine) (1176917-20-6,934201-66-8)

Guidance literature:

In acetonitrile; addn. of pyridine to suspn. of palladium compd. in acetonitrile, stirring until solids dissolved, addn. of iminoiodinane deriv., stirring at room temp. for 8 h; evapn., recrystn. (CH2Cl2/ether) 2 times, washing with ether, elem. anal.;

DOI:10.1021/om061052l

Reference yield: 93.0%

pyridine (110-86-1) + PdCl(N(C6H4NO2)C13H8N)(pyridine) (1176917-20-6,934201-66-8) → Pd(C5H5N)(C13H8N2SO2C6H4NO2)(C5H5N)(1+)*BF4(1-)=(Pd(C5H5N)(C13H8N2SO2C6H4NO2)(NC5H5))(BF4) (1063716-92-6)

Guidance literature:

PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine); With silver tetrafluoroborate; In acetonitrile; at 23 ℃; for 1h;

pyridine; In acetonitrile;

upstream raw materials:

pyridine

[N-(nosyl)imino]phenyliodinane

bis(benzo[h]quinolinato-C(12)N(1))(μ-chlorido)palladium(II)

(acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)

Downstream raw materials:

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(NCCH₃)⁽¹⁺⁾*BF₄^(1-)=(Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(NCCH₃))(BF₄)

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(C₅H₅N)⁽¹⁺⁾*BF₄^(1-)=(Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(NC₅H₅))(BF₄)

(acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)