(acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)

Base Information

• Chemical Name: (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)
• CAS No.: 1063716-38-0
• Molecular Formula: C₂₆H₂₀N₄O₆PdS
• Molecular Weight: 622.954
• Mol file: 1063716-38-0.mol

Synonyms:(acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)

Chemical Property of (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II)

There total 2 articles about (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

PdCl(N(C6H4NO2)C13H8N)(pyridine) (1176917-20-6,934201-66-8) + silver(I) acetate (563-63-3) → (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II) (1063716-38-0)

Guidance literature:

In dichloromethane; at 23 - 40 ℃;

Reference yield:

pyridine (110-86-1) + bis(benzo[h]quinolinato-C(12)N(1))(μ-chlorido)palladium(II) (31114-75-7,25794-30-3) + PhINSO2(4-NO2-C6H4) + silver(I) acetate (563-63-3) → (acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II) (1063716-38-0)

Guidance literature:

In pyridine; sulfonamide insertion into palladium-carbon bond;

DOI:10.1002/anie.200802164

Reference yield: 91.0%

(acetato){benzo[h]quinolin-10-yl-(4-nitrophenylsulfonyl)amide}(pyridine)palladium(II) (1063716-38-0) + 4-biphenylboronic acid (5122-94-1) → Pd(C5H5N)(C13H8N2SO2C6H4NO2)(C6H4C6H5) (1063716-60-8)

Guidance literature:

With potassium carbonate; In methanol; benzene; transmetallation at 23 °C for 2-18 h in 1:1 CH3OH/C6H6; chromy. (silica gel);

DOI:10.1002/anie.200802164

upstream raw materials:

pyridine

bis(benzo[h]quinolinato-C(12)N(1))(μ-chlorido)palladium(II)

silver(I) acetate

PdCl(N(C₆H₄NO₂)C₁₃H₈N)(pyridine)

Downstream raw materials:

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(C₆H₄C(CH₃)3)

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(C₆H₄Br)

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(C₆H₄OH)

Pd(C₅H₅N)(C₁₃H₈N₂SO₂C₆H₄NO₂)(C₆H₃ClCH₃)