meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)

Base Information

• Chemical Name: meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)
• CAS No.: 1376706-56-7
• Molecular Formula: C₄₀H₃₈Cl₂SiZr
• Molecular Weight: 708.957
• Mol file: 1376706-56-7.mol

Synonyms:

Chemical Property of meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)

There total 1 articles about meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 5.0%

dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane (1376706-54-5) + zirconium(IV) chloride (10026-11-6) → meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV) (1376706-56-7)

Guidance literature:

With n-BuLi; In diethyl ether; pentane; (Ar) to soln. ligand in Et2O at -40°C n-BuLi in hexane was added,allowed to warm to room temp., stirred for 3 h and evapd., residue was suspended in pentane, ZrCl4 was added at -60°C, Et2O was added, w armed to room temp., stirred for 16 h; soln. was filtrered, solid was dried, DME and LiCl were added, refluxed for 6 h, solvent was evapd., residue was crystd. from Et2O-hexane;

DOI:10.1021/om300311k

upstream raw materials:

dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

zirconium(IV) chloride