dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

Base Information

Chemical Name:dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane
CAS No.:1376706-54-5
Molecular Formula:C₄₀H₄₀Si
Molecular Weight:548.843
Hs Code.:

Synonyms:

Suppliers and Price of dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

There total 1 articles about dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 856413-75-7
6-methyl-8-phenyl-1,2,3,5-tetrahydro-s-indacene

: 75-78-5,30107-43-8
dimethylsilicon dichloride

: 1376706-54-5
dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

Guidance literature:: 6-methyl-8-phenyl-1,2,3,5-tetrahydro-s-indacene; With n-butyllithium; In diethyl ether; hexane; at -40 - 20 ℃; Inert atmosphere;

dimethylsilicon dichloride; With copper(l) cyanide; In diethyl ether; hexane; at -60 - 20 ℃; Inert atmosphere;
DOI:10.1021/om300311k

Reference yield: 55.0%

: 75-77-4
chloro-trimethyl-silane

: zirconium chloride-tetrahydrofuran

: 1376706-54-5
dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

: 75-64-9
tert-butylamine

: rac-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)

Guidance literature:: With n-BuLi; In tetrahydrofuran; toluene; (Ar) n-BuLi in hexane was added at -20°C to t-BuNH2 in THF-toluene, 2 h at r.t.,added at 0°C to ZrCl4*2THF in toluene, 2 h at r.t., added to soln. prepared from ligand and n-BuLi in THF-toluene, 16 h, Me3SiClwas added, 1 h; hexane was added, solvent was concd. in vacuo, ppt. was filtered out, washed with pentane and dried in vacuo; elem. anal.;
DOI:10.1021/om300311k

Reference yield: 5.0%

: 1376706-54-5
dimethylbis(2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl)silane

: 10026-11-6
zirconium(IV) chloride

: 1376706-56-7
meso-μ-(bis[η5-2-methyl-4-phenyl-1,5,6,7-tetrahydro-s-indacen-1-yl]dimethylsilanediyl)dichlorozirconium(IV)

Guidance literature:: With n-BuLi; In diethyl ether; pentane; (Ar) to soln. ligand in Et2O at -40°C n-BuLi in hexane was added,allowed to warm to room temp., stirred for 3 h and evapd., residue was suspended in pentane, ZrCl4 was added at -60°C, Et2O was added, w armed to room temp., stirred for 16 h; soln. was filtrered, solid was dried, DME and LiCl were added, refluxed for 6 h, solvent was evapd., residue was crystd. from Et2O-hexane;
DOI:10.1021/om300311k