cis dichlorobispyridine palladium (II)

Base Information

• Chemical Name: cis dichlorobispyridine palladium (II)
• CAS No.: 14052-12-1
• Molecular Formula: C₁₀H₁₀Cl₂N₂Pd
• Molecular Weight: 335.529
• Mol file: 14052-12-1.mol

Synonyms:

Chemical Property of cis dichlorobispyridine palladium (II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of cis dichlorobispyridine palladium (II)

There total 22 articles about cis dichlorobispyridine palladium (II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

pyridinium tetrachloropalladate (II) → trans dichlorobispyridine palladium (II) (14872-20-9,15227-47-1,14052-12-1)

Guidance literature:

In neat (no solvent); byproducts: HCl; isothermal decompn. at 140°C; elem. anal.;

Reference yield: 93.0%

pyridine (110-86-1) + palladium dichloride → dichlorobis(pyridine)palladium(II) (14872-20-9,15227-47-1,14052-12-1)

Guidance literature:

In methanol; at 20 ℃; for 3h;

DOI:10.1039/d0cc02262d

Reference yield: 90.0%

N-benzyl-2-methylimidazole (13750-62-4) + chloroacetone (78-95-5) → trans dichlorobispyridine palladium (II) (14872-20-9,15227-47-1,14052-12-1) + C14H17N2O(1+)*Cl(1-)

Guidance literature:

In tetrahydrofuran; for 48h; Inert atmosphere; Schlenk technique; Reflux;

DOI:10.1021/om500834y

upstream raw materials:

bis(μ-chloro)bis[1-3-η3-(1-chloromethyl)-1-buten-3-yl]dipalladium(II)

pyridine

PdCl₂(P(C₆H₅)(2-C₆H₄Cl)2)2

pyridine-2-carbaldehyde

Downstream raw materials:

cis-[Pd(CH₂Ph)2(pyridine)2]

bis(aniline)dichloridopalladium(II)

cis-[Pd(C₆F₅)2(py)2]