[SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

Base Information

Chemical Name:[SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)
CAS No.:160952-08-9
Molecular Formula:C₁₃H₁₄Cl₂NPPd
Molecular Weight:392.561
Hs Code.:

Synonyms:

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Chemical Property of [SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

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Technology Process of [SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

There total 2 articles about [SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 91.0%

: [SP-4-2-(R),(S)]-[(2-aminophenyl)methylphenylphosphine-N,P](1-(1-(dimethylamino)ethyl)naphthyl-C⁽²⁾,N)palladium(II) hexafluorophosphate

: 160952-08-9,161025-04-3,161025-03-2
[SP-4-2-(R)]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

Guidance literature:: With H₂SO₄; LiCl; In sulfuric acid; Ar-atmosphere; dissoln. of Pd-complex in concd. H2SO4, pouring onto ice, addn. of large excess of LiCl; extn. (CH2Cl2), washing of water layer (CH2Cl2), drying of combined org. layers (MgSO4), solvent removal, recrystn. (hot MeOH); elem. anal.;

Reference yield: 77.0%

: ammonium hexafluorophosphate

: 18987-59-2
di-μ-chloro-bis[2-(dimethylaminomethyl)phenyl-C(1),N]dipalladium(II)

: 140669-67-6
(+/-)-(2-aminophenyl)methylphenylphosphine

: 160952-08-9,161025-04-3,161025-03-2
(+/-)[SP-4-2]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

Guidance literature:: With HCl; In methanol; water; Ar-atmosphere; slow addn. of 2 equiv. of phosphine to Pd-complex soln. (in MeOH), addn. of aq. NH4PF6 (pptn.), collection, drying (vac.), dissoln. in acetone, addn. of 10 M HCl; recrystn. (hot MeOH); elem. anal.;

Reference yield: 63.0%

: 160952-08-9,161025-04-3,161025-03-2
(+/-)[SP-4-2]-[(2-aminophenyl)methylphenylphosphine-N,P]dichloropalladium(II)

: 62-76-0
sodium oxalate

: 199296-98-5
[SP-4-2]-[(+/-)-(2-aminophenyl)methylphenylphosphine-P]oxalatopalladium(II)

Guidance literature:: With AgNO₃; In water; acetonitrile; byproducts: AgCl; (argon); addn. of aq. AgNO3 to the Pd complex in MeCN, stirring in absence of light overnight, filtration, addn. of aq. sodium oxalate, stirring(3 h); redn. of volume, filtration, washing (H2O; MeOH/Et2O; Et2O), drying (vac.); elem. anal.;