140669-67-6Relevant academic research and scientific papers
Synthesis, Resolution and Reactions of (+/-)-(2-Aminophenyl)methylphenylphosphine. Crystal and Molecular Structure of (R*,R*,S*,R*)-(+/-)-(1,3-Bisamino>propane)nickel(II) Perchlorate
Barclay, Caroline E.,Deeble, Geoffrey,Doyle, Roy J.,Elix, Sharon A.,Salem, Geoffrey,et al.
, p. 57 - 66 (2007/10/02)
Asymmetric bidentate (+/-)-(2-aminophenyl)methylphenylphosphine has been prepared in 80percent yield from (2-aminophenyl) diphenylphosphine via the secondary phosphine (+/-)-(2-aminophenyl)phenylphosphine.The chiral tertiary phosphine has been resolved by
Completely Stereoselective Synthesis of a Chiral Quadridentate Ligand with As2NP Donor Atoms. Crystal and Molecular Structure of *,S*)>-(+/-)-Dichloro--2-<(2-aminophenyl)methylphosph
Doyle, Roy J.,Salem, Geoffrey,Willis, Anthony C.
, p. 1587 - 1588 (2007/10/02)
Reaction of (+/-)-(2-aminophenyl)(2-chlorophenyl)methylphosphine with sodium (2-dimethylarsinophenyl)methylarsenide is completely stereoselective giving (R*,S*)-1--2-(2-aminophenyl)methylphosphi
Preparation of Hybrid Bidentate Phosphine Ligands by Reduction of Their Benzyl- or Phenyl-phosphonium Salts. X-Ray Crystal Structure of 2-Aminophenyltriphenylphosphonium Tetrachloronickelate(II)
Cooper, Mervyn K.,Downes, J. Michael,Duckworth, Paul A.,Tiekink, Edward R. T.
, p. 595 - 609 (2007/10/02)
The 2-substituted phenylphosphine bidentate hybrid ligands, 2-aminophenyl-, 2-methylaminophenyl-, 2-hydroxyphenyl- and (2-amino-3-methylphenyl)-diphenylphosphine, (1a-d), respectively, and 2-aminophenylmethylphenylphosphine, (1e), were synthesized by reduction of their phenylphosphonium halides, (2a-e)X (X = Cl or Br), with sodium naphthalenide in tetrahydrofuran at -68 deg, or electrochemically at a mercury cathode.The phosphonium salts were prepared by reaction of triphenylphosphine with aryl halide and anhydrous nickel halide at 200 deg.X-Ray diffraction of (2a)2 showed it to have monoclinic space group P21/n, a 10.657(4), b 20.966(3), c 20.422(6) Angstroem, β 101.33(2) deg and Z 4.The structure was refined by a full-matrix least-squares procedure to a final R 0.050 for 3534 reflections with I > 2.5?(I).
