{cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}

Base Information

• Chemical Name: {cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}
• CAS No.: 88867-59-8
• Molecular Formula: C₅₁H₄₄As₂Cl₃OP₂PtRh
• Molecular Weight: 1289.04
• Mol file: 88867-59-8.mol

Synonyms:

Chemical Property of {cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl}

There total 4 articles about {cis-Cl₂(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

di(rhodium)tetracarbonyl dichloride + cis-dichloro-bis((diphenylphosphino)(diphenylarsino)methane)platinum(II) (89144-43-4) → bis(μ-(diphenylphosphino)(diphenylarsino)methane)-trans-carbonylchlororohodium(I)-cis-dichloroplatinum(II) (88867-59-8)

Guidance literature:

In dichloromethane; the soln. of the Rh complex was added to the soln. of the Pt complex at -5°C and stirred for 10 min; the solvent was removed in vac. at 25°C, the soln. was filtered, cooled on ice/acetone bath, pptd. with methanol, ppt. was filtered off, washed with methanol and ether, dried in vac. at 25°C, elem. anal.;

Reference yield:

<(Diphenylarsino)methyl>diphenylphosphan (69783-37-5) → bis(μ-(diphenylphosphino)(diphenylarsino)methane)-trans-carbonylchlororohodium(I)-cis-dichloroplatinum(II) (88867-59-8)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane

In dichloromethane;

Reference yield:

<(Diphenylarsino)methyl>diphenylphosphan (69783-37-5) → {cis-Cl2(platinum)(mu.-(diphenylphosphino)(diphenylarsino)methane)2-trans-(rhodium)(CO)Cl} (88867-59-8,88928-90-9)

Guidance literature:

Multi-step reaction with 2 steps

1: dichloromethane

2: dichloromethane

In dichloromethane;

upstream raw materials:

cis-dichloro-bis((diphenylphosphino)(diphenylarsino)methane)platinum(II)

<(Diphenylarsino)methyl>diphenylphosphan

Downstream raw materials:

trans-Rh(CO)Cl(μ-Ph2AsCH2PPh2)2-trans-PtCl2

RhCOI₂((C₆H₅)4CH₂AsP)2PtI

RhCOCl((C₆H₅)4CH₂AsP)2PtCl₂

((diphenylphosphino)(diphenylarsino)methane)dichloroplatinum(II)