FeH₂(CO)2(P(C₆H₅)2OC₂H₅)2

Base Information

• Chemical Name: FeH₂(CO)2(P(C₆H₅)2OC₂H₅)2
• CAS No.: 214973-79-2
• Molecular Formula: C₃₀H₃₂FeO₄P₂
• Molecular Weight: 574.376
• Mol file: 214973-79-2.mol

Synonyms:

Chemical Property of FeH₂(CO)2(P(C₆H₅)2OC₂H₅)2

Chemical Property:

Purity/Quality:

Safty Information:

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Technology Process of FeH₂(CO)2(P(C₆H₅)2OC₂H₅)2

There total 1 articles about FeH₂(CO)2(P(C₆H₅)2OC₂H₅)2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

Ethyl diphenylphosphinite (719-80-2) + potassium tetracarbonylhydridoferrate (17857-24-8) → FeH2(CO)2(P(C6H5)2OC2H5)2 (214973-79-2)

Guidance literature:

In not given; inert atmosphere; 5 h (according to Brunet et al., Inorg. Synth. 1992, 29, 156); extn. with petroleum ether:C6H6=4:1, crystn. (to give oil);

DOI:10.1021/ic980430e

Reference yield:

FeH2(CO)2(P(C6H5)2OC2H5)2 (214973-79-2) + sodium tetraphenyl borate (143-66-8) + 4,4'-diphenylbisdiazonium ditetrafluoroborate → [(Fe(CO)2(PPh2(OEt))2)2(μ-4,4'-N2C6H4C6H4N2)](BPh4)2

Guidance literature:

In acetone; byproducts: H2; inert atmosphere; addn. of Fe-complex to excess diazonium salt at -80°C, stirring at room temp. for 12 h, filtration, solvent removal (reduced pressure), addn. of EtOH and excess NaBPh4 (pptn. or sepn. of oil); chromy. (SiO2, Me2CO), evapn., trituration with EtOH, collection (filtration), drying (vac.); elem. anal.;

DOI:10.1021/ic980430e

Reference yield:

FeH2(CO)2(P(C6H5)2OC2H5)2 (214973-79-2) + 4-methylbenzenediazonium tetrafluoroborate (459-44-9) + sodium tetraphenyl borate (143-66-8) → [Fe(4-CH3C6H4N2)(CO)2(PPh2OEt)2]BPh4

Guidance literature:

In dichloromethane; byproducts: H2; inert atmosphere; addn. of Fe-complex to excess diazonium salt at -80°C, stirring at room temp. for 7-8 h, filtration, solvent removal (reduced pressure), addn. of EtOH and excess NaBPh4; chromy. (SiO2, Me2CO), evapn., trituration with EtOH, collection (filtration), drying (vac.); elem. anal.;

DOI:10.1021/ic980430e

upstream raw materials:

Ethyl diphenylphosphinite

potassium tetracarbonylhydridoferrate