methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

Base Information

Chemical Name:methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate
CAS No.:1373344-94-5
Molecular Formula:C₃₃H₃₆O₃
Molecular Weight:480.647
Hs Code.:

Synonyms:

Suppliers and Price of methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

Chemical Property:

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Technology Process of methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

There total 11 articles about methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 943902-73-6
(+)-(S)-methyl 3-[(trityloxy)methyl]pent-4-enoate

: 1373344-94-5
methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

Guidance literature:: Multi-step reaction with 4 steps

1.1: diisobutylaluminium hydride / dichloromethane / -90 °C

2.1: lithium hexamethyldisilazane / 1,2-dimethoxyethane

2.2: -78 - 20 °C

3.1: tetrahydrofuran / 0.08 h / 65 °C / Inert atmosphere

4.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate / water; N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; diisobutylaluminium hydride; caesium carbonate; lithium hexamethyldisilazane; In tetrahydrofuran; 1,2-dimethoxyethane; dichloromethane; water; N,N-dimethyl-formamide; 2.1: Julia-Kocienski olefination / 2.2: Julia-Kocienski olefination / 3.1: Suzuki coupling / 4.1: Suzuki coupling;
DOI:10.1021/jo300519g

Reference yield:

: 6213-88-3
(E)-methyl 3-iodoacrylate

: C₃₇H₄₅BO

: 1373344-94-5
methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

Guidance literature:: (E)-methyl 3-iodoacrylate; C₃₇H₄₅BO; With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate; In water; N,N-dimethyl-formamide; at 20 ℃; Inert atmosphere;

In water;
DOI:10.1021/jo300519g

Reference yield:

: 1373344-87-6
C₂₅H₂₄O₂

: 1373344-94-5
methyl (2E,6R,8E,10E)-6-[[(triphenylmethyl)oxy]methyl]-dodeca-2,8,10-trienoate

Guidance literature:: Multi-step reaction with 3 steps

1.1: potassium hexamethylsilazane / 1,2-dimethoxyethane / -78 - 20 °C

1.2: -78 - 20 °C

2.1: tetrahydrofuran / 0.08 h / 65 °C / Inert atmosphere

3.1: (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; caesium carbonate / water; N,N-dimethyl-formamide / 20 °C / Inert atmosphere

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; triphenyl-arsane; potassium hexamethylsilazane; caesium carbonate; In tetrahydrofuran; 1,2-dimethoxyethane; water; N,N-dimethyl-formamide; 1.1: Julia-Kocienski olefination / 2.1: Suzuki coupling / 3.1: Suzuki coupling;
DOI:10.1021/jo300519g