[Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Base Information

Chemical Name:[Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate
CAS No.:80006-27-5
Molecular Formula:C₆₄H₇₄N₄P₂Re*F₆P
Molecular Weight:1292.44
Hs Code.:

Synonyms:

Suppliers and Price of [Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of [Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of [Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

There total 4 articles about [Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 79.0%

: 17084-13-8
potassium hexafluorophosphate

: 931-53-3
Cyclohexyl isocyanide

: 12103-40-1
bis(triphenylphosphine)-rhenium heptahydride

: 80006-27-5
[Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In methanol; byproducts: H2; under N2, slurry of Re complex in methanol treated with excess of cyclohexyl isocyanide, mixt. refluxed for 3 h, solvent removed under reduced pressure, residue treated with KPF6-satd. acetone, stirred for 2 h; filtered, filtrate evapd., residue washed with water and diethyl ether,dried under vac., elem. anal.;

Reference yield: 45.0%

: 17084-13-8
potassium hexafluorophosphate

: 931-53-3
Cyclohexyl isocyanide

: 25702-61-8
ReH₅(P(C₆H₅)3)2(NH₂C₆H₁₁)

: 80006-27-5
[Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In tetrahydrofuran; under N2, soln. of Re complex and cyclohexyl isocyanide in THF refluxedfor 4 d, solvent evapd. under reduced pressure, residue stirred with KPF6-ethanol slurry for 3 h; filtrate slowly evapd., crystals sepd., washed with water and diethyl ether, dried in vac.;

Reference yield: 45.0%

: 17084-13-8
potassium hexafluorophosphate

: 931-53-3
Cyclohexyl isocyanide

: 12104-75-5,122169-15-7
pentahydridotris(triphenylphosphane)Re(V)

: 80006-27-5
[Re(cyclohexyl isocyanide)4(triphenylphosphine)2] hexafluorophosphate

Guidance literature:: In tetrahydrofuran; under N2, soln. of Re complex and cyclohexyl isocyanide in THF refluxedfor 4 d, solvent evapd. under reduced pressure, residue stirred with KPF6-ethanol slurry for 3 h; filtrate slowly evapd., crystals sepd., washed with water and diethyl ether, dried in vac.;