((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

Base Information

Chemical Name:((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester
CAS No.:477332-07-3
Molecular Formula:C₁₈H₂₇NO₃
Molecular Weight:305.417
Hs Code.:

Synonyms:

Suppliers and Price of ((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of ((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of ((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

There total 1 articles about ((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1779-49-3
Methyltriphenylphosphonium bromide

: ((1R,2R)-1-Benzyloxymethyl-2-methyl-3-oxo-propyl)-carbamic acid tert-butyl ester

: 477332-07-3
((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

Guidance literature:: With n-butyllithium;
DOI:10.1016/S0040-4039(02)01553-8

Reference yield: 84.0%

: 477332-07-3
((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

: 477332-15-3
((1R,2S)-1-Benzyloxymethyl-4-hydroxy-2-methyl-butyl)-carbamic acid tert-butyl ester

Guidance literature:: With sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dihydrogen peroxide;
DOI:10.1016/S0040-4039(02)01553-8

Reference yield:

: 477332-07-3
((1R,2S)-1-Benzyloxymethyl-2-methyl-but-3-enyl)-carbamic acid tert-butyl ester

: 3-(tert-butyl-diphenyl-silanyloxy)-9-(2''-methoxymethoxymethyl-[2,4';2',4'']teroxazol-4-yl)-7-oxo-decanoic acid tert-butyl ester

Guidance literature:: Multi-step reaction with 14 steps

1.1: 84 percent / 9-BBN; H₂O₂; NaOH

2.1: 98 percent / imidazole / dimethylformamide

3.1: 82 percent / BCl₃ / toluene

4.1: 94 percent / DCC; DMAP / CH₂Cl₂

5.1: TFA / CH₂Cl₂

6.1: 68 percent / DCC; HOBT / dimethylformamide

7.1: 100 percent / K₂CO₃; MeOH

8.1: Dess-Martin periodinane

9.1: dibromotetrachloroethane; triphenylphosphine; 2,6-lutidine

9.2: 90 percent / DBU / acetonitrile

10.1: 92 percent / TBAF; AcOH / CH₂Cl₂

11.1: 98 percent / Dess-Martin periodinane

12.1: 78 percent / CrCl₂; NiCl₂ / tetrahydrofuran; dimethylsulfoxide

13.1: 99 percent / Dess-Martin periodinane

14.1: 100 percent / PPh₃; TBAF; PhMe₂SiH / CuCl

With 1H-imidazole; 2,6-dimethylpyridine; chromium dichloride; methanol; dmap; sodium hydroxide; 9-borabicyclo[3.3.1]nonane dimer; dibromotetrachloroethane; Dimethylphenylsilane; tetrabutyl ammonium fluoride; dihydrogen peroxide; boron trichloride; potassium carbonate; benzotriazol-1-ol; Dess-Martin periodane; acetic acid; dicyclohexyl-carbodiimide; triphenylphosphine; trifluoroacetic acid; nickel dichloride; copper(l) chloride; In tetrahydrofuran; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide; toluene; 12.1: Kishi-Nozaki coupling;
DOI:10.1016/S0040-4039(02)01553-8